This content is not included in your SAE MOBILUS subscription, or you are not logged in.
Round Robin Analysis of Alcohol and Carbonyl Synthetic Exhaust Samples - Coordinating Research Council
ISSN: 0148-7191, e-ISSN: 2688-3627
Published October 01, 1994 by SAE International in United States
Annotation ability available
Recent changes in regulatory practices have brought about a need for speciated analysis of the volatile organic components of vehicle exhaust. The purpose of this study was to allow interested laboratories to participate in a Round Robin so that each could assess their speciation methodologies. “Synthetic exhaust” samples were prepared of mixed DNPH-carbonyl standards deposited on DNPH cartridges, and solutions of alcohol in water. The fifteen participating laboratories included automotive, contract, petroleum and regulatory organizations. The results described in this paper consider only variability associated with the analytical measurement of samples that have already been collected in impingers or on cartridges. In general, alcohols (methanol and ethanol) were quantified without difficulty. With the exception of acrolein and crotonaldehyde, the quantitation of the carbonyl samples was very good considering the variety of analytical methods that were used.
|Technical Paper||Test Fuels: Formulation and Analyses - The Auto/Oil Air Quality Improvement Research Program|
|Technical Paper||Effects of Fuel Properties on Soot Formation in Turbine Combustion|
|Ground Vehicle Standard||Methane Measurement Using Gas Chromatography|
CitationClark, W., Biller, W., Tejada, S., Siegl, W. et al., "Round Robin Analysis of Alcohol and Carbonyl Synthetic Exhaust Samples - Coordinating Research Council," SAE Technical Paper 941944, 1994, https://doi.org/10.4271/941944.
SAE 1994 Transactions: Journal of Fuels and Lubricants
Number: V103-4 ; Published: 1995-09-01
Number: V103-4 ; Published: 1995-09-01
- Jensen T. E., Siegl W. O., Richert, J. F. O., Lipari F., Loo J. F., Prostak A., and Sigsby J., “Advanced Emission Speciation Methodologies for the Auto/Oil Air Quality Improvement Research Program - I. Hydrocarbons and Ethers”, SAE Paper No. 920320, Society of Automotive Engineers, 1992.
- Swarin S. J., Loo J. F., Chladek E., Drouillard M. S., and Tejada S., “Advanced Emission Speciation Methodologies for the Auto/Oil Air Quality Improvement Research Program - II. Aldehydes, Ketones, and Alcohols”, SAE Paper No. 920321, Society of Automotive Engineers, 1992.
- Siegl W. O., Richert J. F. O., Jensen T. E., Schuetzle D., Swarin S. J., Loo J. F., Prostak A., Nagy D., and Schlenker A. M., “Improved Emissions Speciation Methodology for Phase II of the Auto/Oil Air Quality Improvement Research Program. Hydrocarbons and Oxygenates”, SAE Paper No. 930142, Society of Automotive Engineers, 1993.
- Tejada S. B., “The evaluation of Silica Gel Cartridges Coated In Situ with Acidified 2, 4-Dinitrophenylhydrazine for Sampling Aldehydes and Ketones in Air”, International Journal of Environmental Analytical Chemistry, Volume 26, p. 167-185, 1986.
- Risner C. H. and Martin P., “Quantitation of Formaldehyde, Acetaldehyde, and Acetone in Sidestream Cigarette Smoke by High Performance Liquid Chromatography”, Journal of Chromatographic Science, Volume 32, p. 76-82, 1994.
- Winefordner J. D. and Long G. L., “Limit of Detection, a Closer Look at the IUPAC Definition”, Analytical Chemistry, Volume 55, p. 712A-724A, 1983.
- Folet J. P. and Dorsey J. G., “Clarification of the Detection Limit in Chromatography”, Chromatographia, Volume 18, P. 503-511,1984.
- Knoll J. E., “Estimation of the Detection Limit in Chromatography”, Journal of Chromatographic Science, Volume 23, p. 422-425, 1985.
- ACS Committee on Environmental Improvement, MacDoughal Daniel, Chairman, “Guidelines for Data Acquisition and Data Quality Evaluation in Environmental Chemistry”, Analytical Chemistry, Volume 52, p. 2242-2249, 1980.