This content is not included in
your SAE MOBILUS subscription, or you are not logged in.
Utilization of Ruthenium and Ruthenium-Iron Alloys as Bosch Process Catalysts
Annotation ability available
Sector:
Language:
English
Abstract
The Bosch process has been considered as a means to recover oxygen, from metabolic carbon dioxide through the catalytic production of water. Previous investigations have shown that the oxide formation accounts for the limited activity of the iron catalyst. On the other hand, the maximum water concentrations achievable in the nickel and cobalt systems have been shown to correspond to the carbide formation. This paper presents the results of an experimental study carried out to determine the effectiveness of ruthenium and its alloy with iron as alternative Bosch catalysts. Carbon deposition boundaries over the alloy catalysts are reported.
Recommended Content
Authors
- Chartsiri Sophonpanich - Department of Chemical Engineering Massachusetts Institute of Technology Cambridge, MA
- Michael P. Manning - Department of Chemical Engineering Massachusetts Institute of Technology Cambridge, MA
- Robert C. Reid - Department of Chemical Engineering Massachusetts Institute of Technology Cambridge, MA
Citation
Sophonpanich, C., Manning, M., and Reid, R., "Utilization of Ruthenium and Ruthenium-Iron Alloys as Bosch Process Catalysts," SAE Technical Paper 820875, 1982, https://doi.org/10.4271/820875.Also In
References
- Reid R. C. “University Role in Astronaut Life Support Systems: Atmosphere.” May 1970
- Holmes R. F. Keller E. F. King C. D. “A Carbon Dioxide Reduction Unit Using Bosch Reaction and Expendable Catalyst Cartridge.” November 1970
- Holmes R. F. Keller E. F. King C. D. “Bosch CO 2 Reduction System Development.” April 1976
- Heppner D. B. Hallick T. M. Clark D. C. Quattrone P. D. “Bosch: An Alternate CO 2 Reduction Technology.” ASME Paper No. 79-ENAs-32 July 1979
- Manning M. P. “An Investigation of the Bosch Process.” Massachusetts Institute of Technology 1976
- Manning M. P. Reid R. C. “Carbon Dioxide Reduction by Bosch Process.” ASME Paper No. 75-ENAs-22 July 1975
- Sacco A. “An Investigation of the Reactions of Carbon Dioxide, Carbon Monoxide, Methane, Hydrogen and Water over Iron, Iron Carbides, and Iron Oxides.” 1977
- Sacco A. Reid R. C. “Limitations on Water Production in the Iron-Catalyzed Bosch Process.” ASME Paper No. 78-ENAs-4 July 1978
- Garmirian J. E. “Carbon Deposition in a Bosch Process Using a Carbon and Nickel Catalyst,” 1980
- Garmirian J. E. Manning M. P. Reid R. C. “The Use of Nickel and Cobalt Catalysts in a Bosch Reactor.” ASME Paper No. 80-ENAs-15 July 1980
- Rabo J. A. Reisch A. P. Poutsma M. L. “Reactions of Carbon Monoxide and Hydrogen on Co, Ni, Ru and Pd Metals.” J. Catalysis 53 295 1978
- Bell W. E. Tagami M. “High-Temperature Chemistry of the Ruthenium-Oxygen System.” J. Phys. Chem. 67 2432 1963
- Levy R. B. “Properties of Carbides, Nitrides and Borides: Implications for Catalysis.” “Advanced Materials in Catalysis.” New York Academic Press 1977
- Ott G. L. Fleisch T. Delgass W. N. “Fischer-Tropsch Synthesis over Freshly Reduced Iron-Ruthenium Alloy.” J. Catalysis 60 394 1979
- Baker R. T. K. “The Formation of Filamentous Carbon.” “Chemistry and Physics of Carbon,” 14 1979
- Dent J. F. Moignard L. A. Blackgraun W. H. Herbden D. “An Investigation into the Catalytic Synthesis of Methane by Town Gas Manufacturing,” 1945
- Rostrup-Nielsen J. R. “Equilibrium of Decomposition Reactions of Carbon Monoxide and Methane over Nickel Catalysts.” J. Catalysis 27 343 1972
- Browning L. C. Emmett P. H. “Equilibrium Measurements in the Ni 3 C-Ni-CH 4 -H 2 and Co 2 C-Co-CH 4 -H 2 Systems.” J. Am. Chem. Soc. 74 1680 1952
- Hofer L. J. E. Cohn E. M. Peebles W. C. “Isothermal Decomposition of the Carbides in a Carburized Cobalt Fischer-Tropsch Catalyst. J. Phys. Col. Chem. 53 661 1949
- Hofer L. J. E. Cohn E. M. Peebles W. C. “Isothermal Decomposition of Nickel Carbide.” J. Phys. Col. Chem. 54 1161 1950
- Nagakura S. “Study of Metallic Carbides by Electron Diffraction: Part I. Formation and Decomposition of Nickel Carbide.” J. Phys. Soc. of Japan 12 5 482 1957
- Nagakura S. “Study of Metallic Carbides by Electron Diffraction: Part IV. Cobalt Carbides.” J. Phys. Soc. of Japan 16 6 1213 1961
- Ott G. L. Fleisch T. Delgass W. N. “Carbon Deposition and Activity Changes over RuFe Alloys during Fischer-Tropsch Synthesis.” J. Catalysis 65 253 1980
- Fleisch T. Delgass W. N. Winograd N. “Secondary Ion Mass Spectrometry/X-Ray Photoelectron Spectroscopy Study of CO Adsorption on Ni and of Fischer-Tropsch Synthesis on FeRu Alloys.” Surface and Interface Analysis 3 1 23 1981
- McKee D. W. “Interaction of Hydrogen and Carbon Monoxide on Platinum Group Metals.” J. Catalysis 8 240 1967
- Singh K. J. Grenga H. E. “Catalytic Decomposition of Carbon Monoxide on Single Crystalline Ruthenium.” J. Catalysis 47 328 1977
- Ekerdt J. G. Bell A. “Synthesis of Hydrocarbons from CO and H 2 over Silica-Supported Ru: Reaction Rate Measurements and Infrared Spectra of Adsorbed Species.” J. Catalysis 57 397 1979
- Low G. G. Eell A. “Studies of CO Deposition and Reaction with H 2 on Alumina-Supported Ru.” J. Catalysis 57 397 1979
- King D. L. “A Fischer-Tropsch Study of Supported Ruthenium Catalysts,” J. Catalysis 51 386 1978
- Ott G. L. Delgass W. N. Winograd N. Baitinger W. E. “X-Ray Photoelectron Spectroscopy/Secondary Ion Mass Spectrometry of FeRu Alloy Catalysts.” J. Catalysis 56 174 1979
- Good M. L. Akbarnejad M. Patil M. D. Donner J. T. “Utility of the Mössbauer Effect in the Assessment of Chemical Transformations in Unsupported Catalyst Systems as a Function of the Metal Salt,” “Nuclear and Electron Resonance Spectroscopies Applied to Materials Science,” Kaufmann Shenoy New York Elsevier North Holland 271 1981
- Shunk F. A. “Constitution of Binary Alloys, Second Supplement.” New York McGraw-Hill 1969
- Hansen M. “Constitution of Binary Alloys.” New York McGraw-Hill 1958
- Elliott R. P. “Constitution of Binary Alloys, First Supplement.” New York McGraw-Hill 1965