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Removal of Lead Contamination from Unleaded Gasoline
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English
Abstract
Various systems were developed for deleading contaminated unleaded gasoline. As shown in both laboratory and pilot plant studies, the most promising systems consisted of passing gasoline through a fixed bed of carbon or silica gel impregnated with cupric chloride. The carbon system was most effective for removal of tetraethyl lead; the silica gel system was preferred for removal of the equilibrated mix of tetraethyl and tetramethyl leads. The effect of various parameters on deleading activity is discussed. The deleading process was demonstrated to be feasible on a service station scale.
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Citation
Zimmerman, A., Musser, G., Kraus, B., Godici, P. et al., "Removal of Lead Contamination from Unleaded Gasoline," SAE Technical Paper 750695, 1975, https://doi.org/10.4271/750695.Also In
References
- Federal Register 38 6 January 10 1973
- Duffy L. J. Everett N. R. Sevcik J. J. Piehl F. J. “Keeping the Lead Out of Unleaded Gasolines.” 37th Midyear Meeting, API Division of Refining New York 1972
- API Motor Fuels Subcommittee Meeting Chicago July 1973
- Soroos H. Shapiro H. “Development of a Chemical Process for Deleading Gasoline,” Final Report. O.S.R.D. Rept. 3018 1943
- Fichter H. L. “Removal of Tetraethyllead from Gasoline” Army Air Forces Eng. Div. 1945
- Calingaert G. Soroos H. Shapiro H. “Process of Deleading Gasoline.” December 1945
- Friedman M. “Method for the Removal of Tetraethyl Lead from Hydrocarbons.” January 1946
- Kharasch M. S. “Process of Deleading Gasoline.” November 1948
- Kharasch M. S. “Deleading of Gasoline.” April 1950
- Neef, F. E. Jr. “Method of Removing Dye and Tetraethyl Lead from Gasoline.” January 1945
- Rasmussen S. “Method and Apparatus for Removing Lead Containing Ingredients from Hydrocarbon Fuels.” August 1948
- Rifkin E. B. Ewen D. H. “Deleading Gasoline.” December 1951
- Breynan Th. “About a Reaction Between Tetraethyl Lead and Ferrous Chloride.” Angew. Chem. 62 1950 430
- Choudhuri B. K. Viswanathan C. R. Vats S. S. Aiyar A. R. “Deleading of Gasoline.” Defence Sci. J. 11 1961 34 44
- Moss R. Upton C. Campbell K. Griffiths S. T. “Extraction of Lead from Petroleum Products Employing Aqueous Iodine Monochloride.” December 1969
- Shapiro A. Olson D. A. H. “Removal of Tetraethyl Lead from Hydrocarbon Liquids with Sulfur Dioxide.” January 1961
- Crook E. H. Kittle P. A. “Removal of Residual Organoleads from Organic Liquids.” September 1974
- Whitehurst D. D. Butter S. A. Rodewald, P. G. Jr. “Sorbent for Removal of Heavy Metals.” February 1974
- Whitehurst D. D. “Sorbent and Process for Heavy Metal Removal from Motor Fuel,” January 1974
- Heilweil I. J. “Lead Trap.” March 1974
- Whitehurst D.D. “Sorbent for Heavy Metals.” December 1974 April 1975
- Shapiro H. Frey F. W. “The Organic Compounds of Lead.” New York John Wiley and Sons, Inc., Interscience Div. 1968 77 89
- Ginderow D. Setton R. “Insertion of FeCls into Graphite with Solutions of the Halide.” Compt. Rend. 257 1963 687 689
- Ogloblina I. P. et. al. “Preparation and Use of Highly Pure Adsorbents.” Soviet Symposium on Adsorption (1969); through Chem. Abstracts 77 1972 281 144177a
- Montarnal R. “Study on the Influence of the Addition of Macroporosity on the Efficiency of a Microporous Catalyst.” Bull. Soc. Chim. France 1965 2019 2029
- Pittsburgh Activated Carbon “Basic Concepts of Adsorption on Activated Carbon.” Pittsburgh 3 9
- Hassler J. W. “Activated Carbon.” New York Chemical Publishing Co. 1951 326 328
- Clinton N. A. Kochi J. K. “Reduction of Copper (II) by Tetraethyllead, Evidence for Ethyl Radicals in Acetic Acid.” J. Organometal. Chem. 42 1972 241 255
- Clinton N. A. Kochi J. K. “Alkylation as a Route to Reduction of Copper (II) By Tetraalkyllead.” J. Organometal. Chem. 56 1973 243 254
- Bawn C. E. H. Whitby F. J. “Alkyl Derivatives of Group I Metals, Part II.” J. Chem. Soc. 1956 3926 3931
- Henderson S. R. Snyder L. J. “Rapid Spectrophotometric Determination of Triethyllead, Diethyllead, and Inorganic Lead Ions.” Anal. Chem. 33 1961 1172 1175
- Clinton N. A. Kochi J. K. “The Catalytic Decomposition of Tetraethyllead by Copper (I).” J. Organometal. Chem. 42 1972 229 240
- Pedersen C. J. “Inhibition of Deterioration of Cracked Gasoline During Storage.” Ind. and Eng. Chem. 41 1948 924 928