This content is not included in
your SAE MOBILUS subscription, or you are not logged in.
Oxidation Stability of Diesel-Biodiesel Blends: Impact of Physical-Chemical Properties Over Ageing into Fuel Injection Systems (FIS) and Storage
Technical Paper
2016-01-2267
ISSN: 0148-7191, e-ISSN: 2688-3627
Annotation ability available
Sector:
Language:
English
Abstract
The increased use of alternative fuels has been linked to deterioration in performance of fuel injection systems as a result of insoluble deposit formation. Here, the impact of Diesel/biodiesel blends formulation and temperature on the oxidation stability was studied based on total acid number (TAN), density, viscosity and surface tension. We have compared fuel oxidation during storage with fuel oxidation into the fuel injection system (FIS) and determined the most important physical-chemical parameters that could be used to follow fuel oxidation on-board. Based on the results obtained, a satisfactory correlation between storage oxidation and fuel on-board degradation was observed. Biodiesel fuel tends to deteriorate during delivery and storage before refueling. Also, fuel ageing on-board is equivalent to 4-5months of storage which means Biodiesel has impact on fuel injection system with long-term storage/parking after high or high-low alternating load operation.
Recommended Content
Authors
Citation
Alves Fortunato, M. and Starck, L., "Oxidation Stability of Diesel-Biodiesel Blends: Impact of Physical-Chemical Properties Over Ageing into Fuel Injection Systems (FIS) and Storage," SAE Technical Paper 2016-01-2267, 2016, https://doi.org/10.4271/2016-01-2267.Also In
References
- Office Journal of the European Union Directive 2009/28/EC of the European Parliament and of the Council of 23 April 2009 on the promotion of the use of energy from renewable sources and amending and subsequently repealing Directives 2001/77/EC and 2003/30/EC
- International Energy Agency World Energy Outlook 2010
- Barker , J. , Reid , J. , Snape , C. , Scurr , D. et al. Spectroscopic Studies of Internal Injector Deposits (IDID) Resulting from the Use of Non-Commercial Low Molecular Weight Polyisobutylenesuccinimide (PIBSI) SAE Int. J. Fuels Lubr. 7 3 762 770 2014 10.4271/2014-01-2720
- Lacey , P. , Gail , S. , Kientz , J. , Benoist , G. et al. Fuel Quality and Diesel Injector Deposits SAE Int. J. Fuels Lubr. 5 3 1187 1198 2012 10.4271/2012-01-1693
- Cardenas Almena , M. , Lucio Esperilla , O. , Martin Manzanero , F. , Murillo Duarte , Y. et al. Internal Diesel Injector Deposits: Sodium Carboxylates of C12 Succinic Acids and C16 and C18 Fatty Acids SAE Technical Paper 2012-01-1689 2012 10.4271/2012-01-1689
- Omori , T. , Tanaka , A. , Yamada , K. , and Bunne , S. Biodiesel deposit formation mechanism and improvement of Fuel Injection Equipment (FIE ): JSAE 20119297 SAE International 2011 1935
- Beate Richter , Svetlana Crusius , Ulrike Shcumann , and Horst Harndorf Characterization of Internal Deposits in common-rail injectors Research Injector Systems MTZ 2013
- Schwab , S. , Bennett , J. , Dell , S. , Galante-Fox , J. et al. Internal Injector Deposits in High-Pressure Common Rail Diesel Engines SAE Int. J. Fuels Lubr. 3 2 865 878 2010 10.4271/2010-01-2242
- Xu , H. , Wang , C. , Ma , X. , Sarangi , A.K. et al. Fuel injector deposits in direct-injection spark-ignition engines Progress in Energy and Combustion Science 50 63 80 2015 10.1016/j.pecs.2015.02.002
- Ben Amara , A. , Lecointe , B. , Jeuland , N. , Takahashi , T. et al. Experimental Study of the Impact of Diesel/Biodiesel Blends Oxidation on the Fuel Injection System SAE Int. J. Fuels Lubr. 7 3 849 860 2014 10.4271/2014-01-2767
- Bouilly , J. , Mohammadi , A. , Iida , Y. , Hashimoto , H. et al. Biodiesel Stability and its Effects on Diesel Fuel Injection Equipment SAE Technical Paper 2012-01-0860 2012 10.4271/2012-01-0860
- Omori , T. , Tanaka , A. , Yamada , K. , and Bunne , S. Biodiesel Fuel Effects on Injection System and Establishment of the Evaluation Method SAE Technical Paper 2011-28-0057 2011 10.4271/2011-28-0057
- Pullen , J. and Saeed , K. An overview of biodiesel oxidation stability Renewable and Sustainable Energy Reviews 16 8 5924 5950 2012 10.1016/j.rser.2012.06.024
- Zhao , H. , Cao , Y. , Orndorff , W. , Cheng , Y.-H. et al. Thermal behaviors of soy biodiesel Journal of Thermal Analysis and Calorimetry 109 3 1145 1150 2012 10.1007/s10973-012-2551-8
- Berrios , M. , Martín , M.a. , Chica , a.F. , and Martín , a. Storage effect in the quality of different methyl esters and blends with diesel Fuel 91 1 119 125 2012 10.1016/j.fuel.2011.07.021
- Bacha , K. , Ben-Amara , A. , Vannier , A. , Alves-Fortunato , M. et al. Oxidation Stability of Diesel/Biodiesel Fuels Measured by a PetroOxy Device and Characterization of Oxidation Products Energy & Fuels 29 7 4345 4355 2015 10.1021/acs.energyfuels.5b00450
- Dunn , R.O. Effect of Temperature on the Oil Stability Index (OSI) of Biodiesel Energy & Fuels 22 1 657 662 2008 10.1021/ef700412c
- Aquino , I.P. , Hernandez , R. P. B. , Chicoma , D.L. , Pinto , H. P. F. et al. Influence of light, temperature and metallic ions on biodiesel degradation and corrosiveness to copper and brass Fuel 102 795 807 2012 10.1016/j.fuel.2012.06.011
- Bouaid , A. , Martinez , M. , and Aracil , J. Long storage stability of biodiesel from vegetable and used frying oils Fuel 86 16 2596 2602 2007 10.1016/j.fuel.2007.02.014
- Soucek , M.D. , Khattab , T. , and Wu , J. Review of autoxidation and driers Progress in Organic Coatings 73 4 435 454 2012 10.1016/j.porgcoat.2011.08.021
- Porter Ned A. and Caldwell Sarah E. and Mills Karen A. Mechanism of free radical oxidation of unsaturated lipids Lipids 30 277 290 1995
- Betts , J. The Kinetics of Hydrocarbon Autoxidation in the Liquid Quarterly Reviews, Chemical Society 265 288 1971
- Roman , O. , Courtois , F. , Maillard , M.-N. , and Riquet , A.-M. Kinetic Study of Hydroperoxide Degradation in Edible Oils Using Electron Spin Resonance Spectroscopy Journal of the American Oil Chemists' Society 1409 1417 2012 10.1007/s11746-012-2048-4
- Fang , H. and McCormick , R. Spectroscopic Study of Biodiesel Degradation Pathways SAE Technical Paper 2006-01-3300 2006 10.4271/2006-01-3300
- Fortunato , M. , Starck , L. , Takahashi , T. , Ohmae , K. et al. Oxidation Stability of Diesel/Biodiesel Blends: Impact of Fuels Physical-Chemical Properties over Ageing During Storage and Accelerated Oxidation SAE Technical Paper 2015-01-1930 2015 10.4271/2015-01-1930
- Dunn , R.O. Thermal Oxidation of Biodiesel by Pressurized Differential Scanning Calorimetry: Effects of Heating Ramp Rate Energy & Fuels 6015 2012