This content is not included in
your SAE MOBILUS subscription, or you are not logged in.
Correlation between Apparent Activation Energy and NO x Emission of Renewable Diesel from Sugar Cane, Biodiesel, Fossil Diesel and their Blends
Technical Paper
2013-36-0249
ISSN: 0148-7191, e-ISSN: 2688-3627
Annotation ability available
Sector:
Language:
English
Abstract
Biofuels and their blends with fossil fuel are important energy resources, which production and application have been largely increased internationally. This study focus on the development of a correlation between apparent activation energy (Ea) and NOx emission of the thermal decomposition of three pure fuels: farnasane (renewable diesel from sugar cane), biodiesel and fossil diesel and their blends. Apparent Activation energy was determined by using thermogravimetry and Model-Free Kinetics. NOx emission was obtained from the European Stationary Cycle (ESC) with OM 926LA CONAMA P7/Euro 5 engine. Results showed that there is a linear correlation between apparent activation energy and NOx emission with R2 of 0,9667 considering pure fuels and their blends which is given as: NOx = 2,2514Ea - 96,309. The average absolute error of this correlation is 2.96% with respect to the measured NOx value. The main advantage of this correlation is its capability to predict NOx emission when either a new pure fuel or a blend of fuels is proposed to use in enginees.
Authors
- Charles C Conconi - Mercedes-Benz do Brasil Ltda
- Aníbal G. Machado - Mercedes-Benz do Brasil Ltda
- Jazon Barros - Mercedes-Benz do Brasil Ltda
- Bernard Muffato Pereira - Mercedes-Benz do Brasil Ltda
- Rogério Piva Cortezi - Mercedes-Benz do Brasil Ltda
- Paula Manoel Crnkovic - Universidade Estadual Paulista “Júlio de Mesquita Filho”
Topic
Citation
Conconi, C., Machado, A., Barros, J., Pereira, B. et al., "Correlation between Apparent Activation Energy and NOx Emission of Renewable Diesel from Sugar Cane, Biodiesel, Fossil Diesel and their Blends," SAE Technical Paper 2013-36-0249, 2013, https://doi.org/10.4271/2013-36-0249.Also In
References
- Henein , N. A. Analysis of pollutant formation and control and fuel economy in diesel-engines Progress in Energy and Combustion Science 1 4 165 207 1976
- Lichty , L. C. Combustion Engine Process New York Mc Graw-Hill 1967
- Saravanan S. , Nagarajan G. , Anand S. , Sampath S. Correlation for thermal NO x formation in compression ignition (CI) engine fuelled with diesel and biodiesel Energy 42 1 June 2012 401 410 0360-5442 10.1016/j.energy.2012.03.028
- Conconi , C. C. , Crnkovic , P. M. Thermal behavior of renewable diesel from sugar cane, biodiesel, fossil diesel and their blends Fuel Fuel Processing Technology 114 0 6 11 10 2013 0378-3820
- Bowman , C. Kinetics of pollutant formation and destruction in combustion Progress in Energy and Combustion Science 1 1 33 45 1975
- Chigier , N. Energy, combustion and environment New York Mcgraw-Hill 1981
- Hill , S. C. ; Douglas Smoot , L. Modeling of nitrogen oxides formation and destruction in combustion systems Progress in Energy and Combustion Science 26 4-6 417 458 8 2000 0360-1285
- Heywood , J. Internal Combustion Engine Fundamentals New York McGraw-Hill 1988
- ANP: AGENCIA NACIONAL DO PETROLEO Resolução ANP 07/08 and ANP 42/09: Especificação do biodiesel Brasilia 2008 http://www.anp.gov.br
- Crnkovic , P. M. et al. Kinetic study of the oxidative degradation of Brazilian fuel oils Energy & Fuels 21 6 3415 3419 2007
- Vyazovkin S , Wight CA Model-free and model-fitting approaches to kinetic analysis of isothermal and nonisothermal data Thermoch Acta 340-341 53 68 1999
- De Jong , E. et al. Promising results with YXY Diesel components in an ESC test cycle using a PACCAR Diesel engine Biomass and Bioenergy 36 0 151 159 1 2012 0961-9534
- AMYRIS http://www.amyrisbiotech.com 29 May 2012
- Ghaly , A. E. ; Ergudenler , A. ; Altaweel , A. M. Determination of the kinetic-parameters of oat straw using thermogravimetric analysis Biomass & Bioenergy 5 6 457 465 1993
- Aligrot , C. ; Champoussin , J. C. ; Guerrassi N. , G. C. Prediction of Self-Ignition Delay of Different Liquid Diesel Fuels International Symposium COMODIA 94 Yokohama, Japan 1994
- Redfern , J. P. applications of thermal-analysis Journal of Thermal Analysis 27 2 427 438 1983
- Rodriguez Fernandez , J. ; Oliva , F. ; Vazquez , R. A. Characterization of the Diesel Soot Oxidation Process through an Optimized Thermogravimetric Method Energy & Fuels 25 5 2039 2048 May 2011 0887-0624
- Sheehan , V. C. , Duffiled J , Garboski M , Shapouri H An overview of biodiesel and petroleum diesel life cycles A report by US Department of Agriculture and Energy 1 35 1998
- Jorgensen , A. ; Bikker , P. ; Herrmann , I. T. Assessing the greenhouse gas emissions from poultry fat biodiesel Journal of Cleaner Production 24 85 91 2012
- Kowalewicz , A. Combustion systems of high-speed piston I. C. engines New York Elsevier 1984
- Ozawa , T. Thermal analysis - review and prospect Thermochimica Acta 355 1-2 35 42 2000