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Universal Rule of Hydrocarbon Oxidation
Technical Paper
2009-01-0948
ISSN: 0148-7191, e-ISSN: 2688-3627
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English
Abstract
Hydrocarbon thermal ignition in internal combustion engines is controlled by the balance of heat release rate by chemical reactions and internal energy formation or removal rate by adiabatic compression or expansion. Heat release rate can be described by a simple “Universal Rule”, that the heat release rate during the thermal ignition preparation period is determined by H2O2 loop composed of four elementary reactions. This rule was validated by sensitivity analysis and response analysis to perturbation of intermediate species concentrations. The rule was applied to clarify several subjects with experimental backgrounds, such as ignition characteristics of higher octane number fuels, an old and well-known knocking model and the influence of H2 addition.
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Citation
Ando, H., Sakai, Y., and Kuwahara, K., "Universal Rule of Hydrocarbon Oxidation," SAE Technical Paper 2009-01-0948, 2009, https://doi.org/10.4271/2009-01-0948.Also In
References
- Pilling M.J. Low Temperature Combustion and Auto- ignition Elsevir Science B. V. 1997
- Kuwahara K. Ando H. “Role of Heat Accumulation by Reaction Loop Initiated by H 2 O 2 Decomposition for Thermal Ignition” SAE Paper 2007-01-0908 2007
- Ando H. Kuwahara K. “Difference of Reaction Schemes on Low Initial Temperature Conditions with LTO Reactions and High Initial Temperature Conditions Skipping Them” COMODIA 2008 2008
- Kuwahara K. Ando H. “Analysis of Hydrocarbon Low-Temperature Oxidation with Contribution Matrices” 19th Internal Combustion Engine Symposium Japan 2007
- Ando H. Ohta Y. Kuwahara K. Sakai Y. “What is X in Livengood Wu Integral?” Paper 20085849 JSAE Academic Conference Fall, 2008
- Homogeneous Charge Compression Ignition (HCCI) Combustion 2006 SAE International, SP2005 2006
- Homogeneous Charge Compression Ignition (HCCI) Combustion 2007 SAE International, SP2100 2007
- Homogeneous Charge Compression Ignition (HCCI) Combustion 2008 SAE International, SP2182 2008
- http://www.reactiondesiqn.com/products/open/chemkin.html
- http://www.cms.llnl.qov/combustion/combustion2.html
- Curran H. J. Gaffuri P. Pitz W. J. Westbrook C. K. “A Comprehensive Modeling Study of n-Heptane Oxidation” Combustion and Flame 114 149 177 1988
- Curran H. J. Gaffuri P. Pitz W. J. Westbrook C. K. “A Comprehensive Modeling Study of iso-Octane Oxidation” Combustion and Flame 129 253 280 2002
- Westbrook C. J. Proceedings of Combustion Institute 28 1563 1577 2000
- Ando H. “Contribution Matrix, a Tool for the Chemical Kinetics Analysis” JSAE Academic Conference 882 363 366 1988
- Livengood J. C. Wu P. C. “Correlation of Autoignition Phenomena in Internal Combustion Engines and Rapid Compression Machines” 5th Symposium on Comb 347 356 1955
- Douaud M. Eyzat P. “Four-Octane-Number-Method for Predicting the Anti-Knock Behavior of Fuels and Engines” SAE Technical Paper 780080 1978
- Ikegami M. Miwa K. Ohmija T Nishitani T. “Study of Ignition Delay of Diesel Spray by Rapid Compression Machine” Transactions of JSME 53 274 281 1987
- Fish I. Read W. S. Affleck W. W. Haskell W. “The controlling Role of-Cool-Flames-in-Two-Stage Ignition” Combust. Flame 13 39 49 1969
- Nose M. Furutani M. Sugimoto T. Ohta Y. “Chemical Species and Luminescence Histories of Piston-compressed Low-Temperature Ignition” Transactions of JSME, 67-661B 2326 2332 2001
- Nose M. Ohta Y. Furutani M. Isogai T. “Accumulations of Carbon Monoxide in Premixed-Piston-Compression Ignition” Transactions of JSME 32-2 11 17 2001
- Furutani M. Ohta Y. Nose M. Isogai T. “Generation / Consumption of Carbon Monoxide in-Blue-Flame Period of Compression ignition of Fuels” 15th Internal Comb. Engine Symposium (Int'l) Seoul 407 412 1999
- Shinagawa T. Okumura T. Furuno S. Kim K-O “Effects of Hydrocarbon Addition to SI Engine on Knock Behavior” SAE Paper 2004-01-1851 2004
- Tunestal P. Christensen M. Patrik Einewall P. “Hydrogen Addition For Improved Lean Burn Capability of Slow and Fast Burning Natural Gas Combustion” SAE Paper 2002-01-2686 2002
- Tully E. J. Heywood J. B. “Lean-Burn Characteristics of a Gasoline Engine Enriched with Hydrogen from a Plasmatron Fuel Reformer” SAE Paper 2003-01-0630 2003
- Kido H. Huang S. Tanoue K. Nitta T. “Improving the Combustion Performance of Lean Hydrogen Mixtures by Hydrogen Addition” 11th Internal Combustion Engine Symposium 23 28 1994
- Shudo T. Ono T. Takahashi T. “Influence of Hydrogen and Carbon Monoxide on HCCI Combustion of DME” 17th Internal combustion Engine Symposium 20026069 53 58 2002
- Meeks E. Westbrook C. K. Ando H. Dean A. M. Koshi M. Lengyel M. Maas I. U. Reitz R. “New Modeling Approaches Using Detailed Kinetics for Advanced Engines” COMODIA 2008 2008
- Ando H. Sakai Y. Hou S. Y. Kuwahara K. “H2O2 Loop model - is it a universal rule?” JSAE Academic Conference Fall, 2009
- Xu F. Faeth G. M. “Structure of soot growth region of laminar premixed methane/oxygen flames” Combustion and Flame 108 640 650 2000