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Safety Issues in the Application of a Flammable Refrigerant Gas in MAC Systems: The OEM Perspective [Revised July, 2009]
Technical Paper
2009-01-0541
ISSN: 0148-7191, e-ISSN: 2688-3627
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English
Abstract
The new F-Gas European Union (EU) Legislation requires car manufacturers to design their vehicles for application of low Global Warming Potential (GWP) refrigerant gasses. Low GWP substitutes to R-134a for Mobile Air Conditioning (MAC) application have to be assessed based on their potential for human exposure in terms of toxicity and flammability. Among the current potential candidates, the present paper deals with the flammability risk assessment of HFO-1234yf. This joint DuPont and Honeywell proposal is a Hydro-Fluoro-Olefin, 2,2,2,3 Tetrafluoroprop-1-ene.
Evaluation includes the following:
- 1The general properties of the refrigerant gas,
- 2The investigation of the areas where critical concentrations may be reached,
- 3The possible ignition sources both for the passengers exposure during the vehicle mission and for professional exposure in the assembly plant or service network workshops,
- 4Full scale tests on vehicle with operating MAC system,
- 5End Of Life (EOL) fate of refrigerant.
The zones where some dangerous concentration may be reached both in the cabin compartment and in the engine bay have been identified, together with the duration of the dangerous occurrence and the potential ignition sources.
The investigation demonstrated that the additional risk caused by the adoption of HFO-1234yf as a substitute for R-134a can be managed and that current know how will allow its safe exploitation in new MACS.
Some complementary design guidelines for the definition of a “robust” packaging of the MAC circuit which have been identified will be summarized.
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Authors
Topic
Citation
Monforte, R. and Caretto, L., "Safety Issues in the Application of a Flammable Refrigerant Gas in MAC Systems: The OEM Perspective [Revised July, 2009]," SAE Technical Paper 2009-01-0541, 2009, https://doi.org/10.4271/2009-01-0541.Also In
References
- Excerpts from W. Atkinson communication “Industry Direction on Replacement Refrigerants” SAE ICCC and SAE 1234 WG Members Sept. 25th 2008
- Karter, Michael J. Jr. Ahrens Marty Fire Analysis and Research Division, National Fire Protection Association “US Vehicle Fire Trends and Patterns” July 2008
- Ahrens Marty Fire Analysis and Research Division, National Fire Protection Association “US Vehicle Fire Trends and Patterns” July 2008
- Minor B. HFO-1234yf Low GWP Refrigerant for MAC Application Washington December 9th 2008
- AEGL (Acute Exposure Guideline Levels) 4 Hydrogen Fluoride National Research Council, National Academies Press Washington, D.C. 2004
- Largent E.J. Fluorosis: The Health Aspects of Fluorine Compounds Columbus, OH Ohio State University Press 34 39 43 48 1961
- Lund K. Ekstand J. Boe J. Sostrand P. Kongreud J. Exposure to hydrogen fluoride: An experimental study in humans of concentrations of fluoride in plasma, symptoms, and lung function Occup. Environ. Med. 54 32 37 1997
- Worneldorf C. King M. Grosshandler W. “Lean Flammability Limit as a Fundamental Refrigerant Property” Building and Fire Research Laboratory, NIST 1995 http://www.fire.nist.gov/bfrlpubs/fire95/PDF/f95083.pdf
- Burgess, Zachariah Tsang & Westmoreland: NIST report “Thermo chemical and kinetic data on Fluorocarbons” http://www.tedpella.com/msds_html/81500msd.htm
- Proust C. Ignition risk of the cooling fluid HFO-1234yf in case of a leakage inside a vehicle: phase 1-theoretical aspects Feb. 2008
- Proust C. Jamois D. Ignition risk of the cooling fluid R1234yf in case of a leakage inside a vehicle: phase 2-measurements Apr. 2008
- Jamois D. Mathieu L. Proust C. Daubech J. Ignition risk of the cooling fluid HFO-1234yf in case of a leakage inside a vehicle: phase 3&4-tests in vehicles Oct. 2008
- Proust C. Daubech J. Jamois D. Mathieu L. Bricout P. Julien B. Ignition of refrigerant oil mixtures on hot surfaces Report N° DRA-2008-98374 Dec. 16th 2008
- SAE CRP1234 DRAFT Final Report Nov. 2008