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Effects of Toluene Addition to Primary Reference Fuel at High Temperature
Technical Paper
2007-01-4104
ISSN: 0148-7191, e-ISSN: 2688-3627
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English
Abstract
The ignition delay times of primary reference fuel (PRF) and toluene mixtures have been measured behind the reflected shock waves. The range of experiments covered combustion of fuel in diluted argon for stoichiometric mixtures, pressures of 2.5 atm, temperatures from 1200-1600 K, 0.4% of fuel concentration. The ignition delay times of n-heptane increased with the addition of toluene. However the ignition delay times of iso-octane decreased with the addition of toluene from 0 to 50% and increased from 50 to 100%. A detailed kinetic model with cross reactions considered in this study can not reproduce the trend of ignition delay times for iso-octane/toluene mixtures. From the reaction path analysis, it was suggested that cross reactions between alkenes and aromatics are required to account for these experimental results.
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Citation
Sakai, Y., Ozawa, H., Ogura, T., Miyoshi, A. et al., "Effects of Toluene Addition to Primary Reference Fuel at High Temperature," SAE Technical Paper 2007-01-4104, 2007, https://doi.org/10.4271/2007-01-4104.Also In
References
- Pitz, W.J. Cernansky, N.P. Dryer, F.L. Egolfopoulos, F.N. Farrell, J.T. Friend, D.G. Pitsch, H. “Development of an Experimental Database and Chemical Kinetic Models for Surrogate Gasoline Fuels” SAE Paper 2007-01-0175
- Ogink, R. Golovitchev, V. “Gasoline HCCI Modeling: An Engine Cycle Simulation Code with a Multi-Zone Combustion Model” SAE Paper 2002-01-1745
- Gauthier, B.M. Davidson, D.F. Hanson, R.K. “Shock tube determination of ignition delay times in full-blend and surrogate fuel mixtures” Combust. Flame 139 300 311 2004
- Chaos, M. Zhao, Z. Kazakov, A. Gokulakrishnan, P. Angioletti, M. Dryer, F.L. “A PRF+Toluene Surrogate Fuel Model for Simulating Gasoline Kinetics” 5 th US Combustion Meeting 2007
- Naik, C.K. Pitz, W.J. Sjöberg, M. Dec, J.E. Orme, J. Curran, H.J. Simmie, J.M. Westbrook, C.K. “Detailed Chemical Kinetic Modeling of Surrogate Fuels for Gasoline and Application to an HCCI Engine” 2005 Joint Meeting of the U.S. Sections of The Combustion Institute
- Yahyaoui, M. Djebaϊli-Chaumeix, N. Dagaut, P. Paillard, C.-E. Gail, S. “Experimental and modeling study of gasoline surrogate mixtures oxidation in jet stirred reactor and shock tube” Proc. Combust.Inst. 31 385 391 2007
- Dagaut, P. Bakali, A.E. Ristori, A. “The combustion of kerosene: Experimental results and kinetic modeling using 1- to 3-component surrogate model fuels” Fuel 85 944 956 2006
- Dagaut, P. “On the kinetics of hydrocarbons oxidation from natural gas to kerosene and diesel fuel” Phys. Chem. Chem. Phys. 4 2079 2094 2002
- Glaude, P.A. Conraud, V. Fournet, R. Battin-Leclerc, F. Cöme, G.M. Scacchi, G. Dagaut, P. Cathonnet, M. “Modeling the Oxidation of Mixtures of Primary Reference Automobile Fuels” Energy & Fuels 16 1186 1195 2002
- Curran, H.J. Pitz, W.J. Westbrook, C.K. Callahan, C.V. Dryer, F.L. “Oxidation of Automotive Primary Reference Fuels at Elevated Pressures” Twenty-Seventh Symposium (International) on Combustion 379 387 1998
- Glaude, P.A. Battin-Leclerc, F. Judenherc, B. Warth, V. Fournet, R. Cöme, G.M. Scacchi, G. Dagaut, P. Cathonnet, M. “Experimental and Modeling Study of the Gas-Phase Oxidation of Methyl and Ethyl Tertiary Butyl Ethers” Combust. Flame 121 345 355 2000
- Klotz, S.D. Brezinsky, K. Glassman, I. “Modeling the Combustion of Toluene-Butane Blends” Twenty-Seventh Symposium (International) on Combustion 337 344 1998
- Andrae, J. Johansson, D. Björnbom, P. Risberg, P. Kalghatgi, G. “Co-oxidation in the auto-ignition of primary reference fuels and n-heptane/toluene blends” Combust. Flame 140 267 286 2005
- Andrae, J.C.G. Björnbom, P. Cracknell, R.F. Kalghatgi, G.T. “Autoignition of toluene reference fuels at high pressures modeled with detailed chemical kinetics” Combust. Flame 149 2 24 2007
- Herzler, J. Fikri, M. Hitzbleck, K. Starke, R. Schulz, C. Roth, P. Kalghatgi, G.T. “Shock-tube study of the autoignition of n-heptane/toluene/air mixtures at intermediate temperatures and high pressures” Combust. Flame 149 25 31 2007
- Vanhove, G. Minetti, R. Touchard, S. Fournet, R. Glaude, P.A. Battin-Leclerc, F. “Experimental and modeling study of the autoignition of 1-hexene/iso-octane mixtures at low temperatures” Combust. Flame 145 272 281 2006
- Vanhove, G. Petit, G. Minetti, R. “Experimental study of the kinetic interactions in the low-temperature autoignition of hydrocarbon binary mixtures and a surrogate fuel” Combust. Flame 145 521 532 2006
- Sakai, Y. Inamura, T. Ogura, T. Koshi, M. Pitz, W.J. “Detailed Kinetic Modeling of Toluene Combustion over a Wide Range of Temperature and Pressure” SAE paper No. 2007-01-1885
- Kee, R. J. Rupley, F. M. Miller, J. A. Coltrin, M. E. Grcar, J. F. Meeks, E. Moffat, H. K. Lutz, A. E. Dixon-Lewis, G. Smooke, M. D. Warnatz, J. Evans, G. H. Larson, R. S. Mitchell, R. E. Petzold, L. R. Reynolds, W. C. Caracotsios, M. Stewart, W. E. Glarborg, P. Wang, C. McLellan, C. L. Asigun, O. Houf, W. G. Chou, C. P. Miller, S. F. Ho, P. Young, P. D. Hodgson, D. W. Petrova, M. V. Puduppakkam, K. V. CHEMIKIN Release 4.1, Reaction Design San Diego, CA 2006
- Miyoshi, A. http://www.frad.t.u-tokyo.ac.jp/∼miyoshi/KUCRS/ Ritter, E.R. Bozzelli, J.W. “THERM: Thermodynamic Property Estimation for Gas Phase Radicals and Molecules,” Int. J. Chem. Kinet. 23 767 778 1991
- Ogura, T. Sakai, Y. Miyoshi, A. Koshi, M. Dagaut, P. “Modeling of the Oxidation of Primary Reference Fuel in the Presence of Oxygenated Improvers: Ethyl Tert-Butyl Ether and Ethanol” Energy and Fuels
- Da Costa, I. Fournet, R. Billaud, F. Battin-Leclerc, F. “Experimental and Modeling Study of the Oxidation of Benzene” Int. J. Chem. Kinet. 35 503 524 2003
- Bounaceur, R. Da Costa, I. Fournet, R. Billaud, F. Battin-Leclerc, F. “Experimental and Modeling Study of the Oxidation of Toluene” Int. J. Chem. Kinet. 37 25 49 2005
- Fahr, A. Stein, S. E. “Reactions vinyl and phenyl radicals with ethyne, ethane and benzene” Twenty-Second Symposium (International) on Combustion 1023 1029 1988
- Tsang, W. “Chemical kinetic data base for combustion chemistry. Part V. Propene” J. Phys. Chem. Ref. Data 20 221 273 1991