This content is not included in
your SAE MOBILUS subscription, or you are not logged in.
Quantification of Biodiesel Content in Fuels and Lubricants by FTIR and NMR Spectroscopy
Technical Paper
2006-01-3301
ISSN: 0148-7191, e-ISSN: 2688-3627
Annotation ability available
Sector:
Language:
English
Abstract
The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content.
We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod). By drying B100 and biodiesel blend samples, the relative standard deviation for the carbonyl band integrated intensity can be decreased five-fold, thus increasing the reliability of the method for quantification of biodiesel content.
A phosphorus nuclear magnetic resonance (31P-NMR) investigation revealed broadening in the bandwidth, due to interactions of the functional groups in zinc-dialkyldithiophosphate (ZDDP) with hydroxyl groups of hydroxy esters. Hydroxy esters serve as models of impurities in biodiesel (mono- or di-glycerides) or biodiesel partial oxidation products. Thus, biodiesel fuel dilution in lubrication oil may impact the antiwear properties of ZDDP through the formation of complexes with ZDDP that prevent the antiwear additives from forming a coating on the metal surface.
Recommended Content
| Technical Paper | Effect of Various Lubricating Oils on Piston Deposits in Biodiesel Fueled Engines |
| Technical Paper | Vegetable Oil with Ester Base as a Two-Cycle SI Engine Lubricant |
| Technical Paper | The Automotive Fuels and Lubricants in China |
Authors
Citation
Fang, H., Alleman, T., and McCormick, R., "Quantification of Biodiesel Content in Fuels and Lubricants by FTIR and NMR Spectroscopy," SAE Technical Paper 2006-01-3301, 2006, https://doi.org/10.4271/2006-01-3301.Also In
References
- Mortier, R. M. Orszulik, S. T. “Chemistry & Technology of Lubricants” Blackie VCH New York 1992
- Fang, H. L. McCormick, R. L. “Spectroscopic Study of Biodiesel Degradation Pathways” SAE 2006-01-3300
- Fang, H. L. Swofford, R. L. “Photoacoustic spectroscopy of vibrational overtones in polyatomic molecules” Appl. Optics 21 55 1982
- Fang, H. L. Meister, D. M. Swofford, R. L. “Overtone spectroscopy of nonequivalent methyl CH oscillators. Influence of conformation on vibrational overtone energies” J. Phys. Chem. 88 410 1984
- Fang, H. L. Compton, D. A. C. “Overtone spectroscopy of nonequivalent CH oscillators in 1-alkenes and dienes” J. Phys. Chem. 92 7185 1988
- Fang, H. L. Stehouwer, D. M. Wang, J. “Interaction between fuel additive and oil contaminant: (II) its impact on fuel stability and filter plugging mechanism” SAE 2003-01-3140
- Harrison, P. G Kikabhai, T. J. Chem. Soc. Dalton Trans. 807 1987