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Surface Engineered Coatings and Surface Additive Interactions for Boundary Film Formation to Reduce Frictional Losses in the Automotive Industry: A review
ISSN: 0148-7191, e-ISSN: 2688-3627
Published May 11, 2005 by SAE International in United States
Annotation ability available
Surface engineering encompasses numerous vital and diverse technologies in the design and wear of automotive and off-highway components. These technologies include CVD, PVD, ion implantation and conventional heat treatments such as carburizing, nitriding and carbonitriding. Although these technologies are well known, it is considerably more difficult to understand the relative importance of the various technology niches for these processes, and it is very difficult to find effective summaries of the impact of these technologies on comparative lubrication formulation and practice. The objectives of this paper are two-fold. One is to review the impact of surface engineered coatings on the surface chemistry of steel. The second objective is to review the impact of the surface chemistry obtained by different surface treatments on boundary film formation to reduce frictional losses during fluid lubrication.
|Technical Paper||Temperature Effects on the Deformation and Fracture of a Quenched-and-Partitioned Steel|
|Aerospace Standard||CLAMP, LOOP TYPE BONDING|
|Aerospace Standard||NUT, SELF-LOCKING, PLATE, ONE LUG, FLOATING, LOW HEIGHT, UNS S66286, CLASS: 125 KSI/800 °F|
- Lauralice C.F. Canale - Depto Eng. Materiais, Aeronáutica e Automobilística. EESC-USP, São Carlos, SP, Brasil. Email: firstname.lastname@example.org
- Guizhen Xu - Department of Mechanical Engineering, Texas A&M University, College Station, TX, USA
- Hong Liang - Department of Mechanical Engineering, Texas A&M University, College Station, TX, USA
- Jiajun Liu - Department of Mechanical Engineering, Tsinghua University, Beijing, China
- George E. Totten - Department of Mechanical and Materials Engineering Portland State University, Portland, OR, USA
CitationCanale, L., Xu, G., Liang, H., Liu, J. et al., "Surface Engineered Coatings and Surface Additive Interactions for Boundary Film Formation to Reduce Frictional Losses in the Automotive Industry: A review," SAE Technical Paper 2005-01-2180, 2005, https://doi.org/10.4271/2005-01-2180.
SAE 2005 Transactions Journal of Fuels and Lubricants
Number: V114-4 ; Published: 2006-02-01
Number: V114-4 ; Published: 2006-02-01
- Nakada M.. Piston and piston ring tribology and fue economy. Proceedings of the International Tribology Conference, Yokohama, 1995. 1667-1671.
- Benchalta M.T. and Lockwood F.E., Reliable model lubricant-related friction in internal combustion engines, Lubrication Science, 1993, 5-4, 259-281.
- Nakada M.. Trends in engine technology and tribology. Tribology International, 1994, 27(1): 3-8.
- Engine performance improvement. Automotive Engineering, 1995, 1: 15-20.
- Liang H., Totten G.E. and Webster G.M., Chapter 35 - Lubrication and tribology fundamentals, in Fuels and Lubricants Handbook: Technology, Properties, Performance and Testing, Eds. Totten G.E., Westbrook S.R. and Shah R.J., ASTM International, West Conshohocken, PA, p. 909-961.
- Stribeck R., Characterization of plain and roller bearings, Zeitung des Vereins Deutscher Ingenieure, 1902, 46, 1341-1348.
- McKee S.A. and McKee T.R., Friction of journal bearings as influenced by clearance and length, Transactions ASME, 1929, 51, 161-171.
- Zaretsky E.V.,STLE Life Factors for Roller Bearings, Society for Tribologists and Lubrication Engineers, Park Ridge, IL, 1992, p. 199-201.
- Schilling G.J. and Bright G.S., Fuel and lubricant additives - II, Lubrication, 1977, 63(2), 13-24.
- Spikes H.A., Additive-additive and additive-surface interactions in lubrication, Lubrication Science, 2-1, 3-23.
- Kajdas C., Engine oil additives: a general review, Mech. Eng., 1993, 80, 149-176.
- Huang Y.W., Cheng G.X., and Dong J.X., Studies on the interrelationships between the character of metals and antiwear additives, Lubrication Science, 2-3, 253-266.
- Kotvis P.V., and Tysoe W.T., Surface chemistry of chlorinated hydrocarbon lubricant additives - Part I: Extreme-pressure tribology, Tribology Transactions, 1998, 41(1), 117-123.
- Sharma J.P. and Cameron A., Surface roughness and load in boundary lubrication, ASLE Transactions, 16(4), 258-265.
- Hsu S.M., Shen M.C., Klaus E.E., Cheng H.S. and Lacey P.I., Mechano-chemical model reaction temperatures in a concentrated contact, Wear, 1994, 175, 209-218.
- Vipper A.P., Bartz W., Karaulov A.K., Mischuk O.A., and Yu. Lukinyuk M., Antifriction action of lubricant additives, Lubrication Science, 1995, 7-3, 247-259.
- Kim S.M, Sit C.Y., Komvopoulos K., Yamaguchi E.S., and Ryason P.R., Boundary lubrication of steel surfaces with borate, phosphorous, and sulfur containing lubricants at relatively low and elevated temperatures, Tribology Transactions, 2000, 43(4), 569-578.
- de Gee A.W., Begellinger A., and Salomon G., Lubricated wear of steel point contacts - application of the transition diagram, Proceedings of the 11th Leeds-Lyon International Conference on Tribology, Paper V(i), University of Leeds, Leeds, UK, 1984, p. 106-116.
- Zum Guhr K.H.. Microstructure and Wear of Materials, Tribology Series, Vol. 10, 1987, Elsevier, Ámsterdam, p. 560 -.
- Canale L.C.F. and Crnkovic O.R., Chapter 14-Heat Treatment: Tribological Applications, in Surface Modifications and Mechanisms: Friction, Stress and Reaction Engineering, Eds. Totten G.E. and Liang H.,, 2004, Marcel Dekker, New York, NY, p. 501-542.
- Wang W., Lei T., and Liu J., Tribo-metallographic behavior of high-carbon steels in dry sliding: III - dynamic microstructural changes and wear, Wear, 1999, 231, p. 20-37.
- Holzhauer W. and Calabrese S.J., Steel hardness effects in boundary lubricated sliding: an in-situ SEM study, Tribology Transactions, 1990, 33(1), 1-10.
- Jisheng E. and Gawne D.T., Effect of treatments on the sliding wear mechanisms of steels under boundary lubrication, Tribology Transactions, 1999, 42(3), 626-632.
- Lansdown A.R., The effects of oxygen availability on the lubricating performance of dimethyl silicone in the boundary regime, Wear, 1994, 175, 25-38.
- Hironaka S., Yagagi Y., and Sakurai T., Effects of some surfactants on antiwear performance, ASLE Transactions, ????, 21(3), 231-235.
- Ma Y., Wu Y., Gu Z., and Liu J., Lubricating mechanisms of sulfurized olefin on oxynitrided steel surface under boundary lubricating condition, Wear, 1996, 194, 174-177.
- Yamamoto Y., Lubrication theory: boundary lubrication, friction and wear, Japanese J. Tribology, 1996, 41(1), 7-11.
- van Dam W., Willis W.W. and Cooper M.W., The impact of additive chemistry and lubricant rheology on wear in heavy duty diesel engines, SAE Technical Paper Series, Paper Number 1999-01-3575, 1999.
- Lansdown A.R., The effects of oxygen availability on the lubricating performance of dimethyl silicone in the boundary regime, Wear, 1994, 175, 25-38.
- Fox M.F., Jones C.J., Picken D.J. and Snow C.G., The “limits of lubrication”concept applied to piston ring zone lubrication of modern engines, Tribology Letters, 1997, 3, 99-106.
- Spikes H.A. and Cann P.M., The thickness and rheology of boundary lubricating films, Proceedings of The International Tribology Conference, 1995, Yokohama, Japan, p. 1089-1094.
- Kim H.W., The viscosity-pressure studies of polymer solutions, Ph.D. Thesis, The Pennsylvania State University, University Park, PA, 1970.
- , Fundamentals of wear, Lubrication, 1956, 42(12), 149-160.
- Sellei H., Sulfurized extreme-pressure lubricants and cutting oils - Part I: literature survey, Petroleum Processing, 1949, September, 1003-1009.
- Forbes E.S., Antiwear and extreme pressure additives for lubricants, Tribology, 1970, 3, 145-162.
- Hironaka S., Working mechanisms of additives in lubricating oils, Sosei to Kako, 1995-1996, 36(413), 579-585.
- Groszek A.J., Heat of adsorption measurements in lubricating oil research, Chemistry and Industry, 1965, March 20, 482-489.
- McFadden C., Soto C., and Spencer N.D., Adsorption and surface chemistry in tribology, Tribology International, 1997, 30(12), 881-888.
- Shaub H., Pandosh J., Searle A., and Sprague S., Mechanism studies with special boundary lubricant chemistry, SAE Technical Paper Series, Technical Paper Number 952475, 1995
- Sheasby J. S., Caughlin T. A., Mackwood W. A.. A comparasion of the boundary lubrication of 52100 steel, zirconia and silicon nitride by S, P, S/P and zinc dialkyl dithiphosphate additives. Wear,1996, 196, 100-109.
- Popov V.L., Smolin I.Yu., Gerv A. and Kehrwald B., Simulation of wear in combustion engines, to be published in Computational Materials Science.
- W•nstrand O., Wear resistant low friction coatings for machine elements, Ph.D. Thesis, Uppsala University, Uppsala, Sweden, 2000.
- Barcroft F.T., A technique for investigating reactions between EP additives and metal at high temperatures, Wear, 1960, 3, 440-453.
- Goldblatt I.L. and Appledorn J.K., The antiwear behavior of TCP in different atmospheres and basestocks, ASLE Transactions, 1969, 13, 203-214.
- Ustrekhova O.A., Ezhikova-Babakhanova T.G. and Wood G.B., Tribological behavior of olefin additives, J. of Friction and Wear, 1995, 16(4), 110-114.
- Hsu S.M., Boundary lubrication: current understanding, Tribology Letters, 1997, 3, 1-11.
- Brenman M. and Lerchenthal Ch.H., Increase of adhesive bond strength through the mechanochemical creation of free radicals: I*, Polymer Engineering and Science, 1976, 16(11), 747-759.
- Bancroft G.M., Kasrai M., Fuller M., Yin Z., Fyfe K. and Tan K.H., Mechanisms of tribochemical film formation: stability of tribo-and thermally-generated ZDDP films, Tribology Letters, 1997, 3, 47-51.
- Martin J.M., Lubricant additives and the chemistry of rubbing surfaces: metal dithiophosphates triboreaction films revisited, Toraiborojisuto, 1997, 42 (9), 724-729.
- Yamaguchi E.S. and Ryason P.R., Structures of adsorbed zinc dithiophosphates and their relationship to engine wear, Tribotest, 1996, 3-2, 123-136.
- ClevengerJ.E., CarlsonD.C. and KleiserW.M.. The effect of engine oil viscosity and composition on fuel efficiency. SAE paper No. 841389, 1984.
- WaguriY., FukushimaA., KitaharaT. et al.. Journal of the Japanese Society of Mechanical Engineering, 1993, 59, 218-225.
- UchidaM. and MasudaY.. Monthly Tribology, 1995, 4, 12-20.
- KennedyS. and MooreL.D.. Additive effects on lubricant fuel economy. SAE paper No. 872121, 1987.
- KuoL.L.K., ChangS.T., HsiehS.K. et al.. Fuel economy engine oils via friction modifiers. Lubrication Engineering, 1989, 45(1): 81-98.
- YamamotoY. and GondoS.. Environmental effects on the composition of surface films produced by Organo-Molybdenum compound. Tribology Transactions, 1994, 37(1): 182-188.
- KikuchiT., YonekuraY. and AkiyamaK.. Frictional characteristics of organomolybdenum compound with addition of sulfurized additives. JSAE, 1995.
- MurakiM. and WadaH.. Frictional properties of organo molybdenum compounds in presence of ZnDTPs under sliding conditions(part 1). J.Jpn.Soc.Tribologists, 1993, 38(10): 919-926.
- YamamotoY. and GondoS.. Tribology Transactions, 1989, 32(2): 251-260.
- ThyamaM. and OhmoriT.. Influence of lubricating oil viscosity and friction modifier on engine parts wear. Japanese Journal of Tribology, 1997, 42(11): 1233-1241.
- IgarashiJ., YamadaY., IshimaruM. et al.. Degradation of friction modifiers. Proceeding of Japan International Tribology Conference, Nagoya, 1990, 421-426.
- OkamotoT., FujitaK. and KawamuraM.. EXAFS and EXANES studies on decomposition of molybdenum O, O-dialkyl phosphorodithioate in commercial engine oils. Bull.Chem.Soc.Jpn., 1988, 6, 916-922.
- AkiyamaK., KikuchiT., SuglyamaS. et al.. Gasoline engine oil durability on fuel economy improvement performance. JSAE, 1995.
- AralK., YamadaM., AsanoS. et al.. Lubricant technology to enhance the durability of low friction performance of gasoline engine oils. SAE paper No. 952533, 1995, 1964-1972.
- JohnsonM.D., JensenR.K. and KorcekS.. Base oil effects on friction reducing capabilities of molybdenum dialkyldithiocarbamate containing engine oils. SAE paper No. 972860, 1997, 1054-1064.
- DavisF.A. and EyreT.S.. The effect of a friction modifier on piston ring and cylinder bore friction and wear. Tribology International, 1990, 23(3): 163-171.
- Taylor L., Spikes H., and Camenzind H., Film-forming properties of zinc-based and ashless antiwear additives, Paper Number 2000-01-2030, 2000.
- NealeM.J.. The tribology of engine design. Journal of Automotive Engineering, 1992, 206: 197-207.
- EyreT.S., DuttaK.K. and DavisF.A.. Characterization and simulation of wear occurring in the cylinder bore of the internal combustion engine. Tribology International, 1990, 23(1): 11-16.
- OotaniT., YahataN., FujikiA. and EhiraA.. Impact wear characteristics of engine valve and valve seat insert materials at high temperature. Wear, 1995, 188: 175-184.
- NarasimhanS.L. and LarsonJ.M.. Valve gear wear and materials. SAE paper No. 851497, 1985.
- Van Dissel,R. BarberG.C., LarsonJ.M. and NarasimhanS.L.. Engine valve seat and insert wear. SAE paper No. 892146, 1989.
- WangY.S., SchaeferS.K., BennettC. and BarberG.C.. Wear mechanisms of valve seat and insert in heavy duty diesel engines. SAE paper No. 952476, 1995.
- GodfreyD. and CourtneyR.L.. Investigation of the mechanism of exhaust valve seat wear in engines run on unleaded gasoline. SAE paper No. 710356, 1971.
- ChaudhuriA.. Hot corrosion of diesel engine exhaust valves. SAE paper No. 730679, 1973.
- WangY.S., NarasimhanS., LarsonJ.M., LarsonJ.E. and BarberG.C.. The effect of operating conditions on heavy duty engine valve seat wear. Wear, 1996, 201: 15-25.
- ZhaoR., BarberG.C., WangY.S. and LarsonJ.E.. Wear mechanism analysis of engine exhaust valve seats with a laboratory simulator. Tribology Transactions, 1997, 40(2): 209-218.
- Liu Zuomin and ChildsT.H.C.. Material dissipative processes in automotive engine exhaust valve-seat wear. Dissipative Processes in Tribology. 1994, 445-451.
- JohnsonV.A. and GalenC.W.. Diesel exhaust valves. SAE paper No. 660034, 1966.
- JenkinsL.F. and LarsonJ.M.. The development of a new austen stainless steel exhaust valve material. SAE paper No. 780245, 1978.
- KanoM. and TanimotoI.. Wear mechanism of high wear-resistant materials for automotive valve trains. Wear of Materials, ASME, 1991, 83-89.
- GarwoodM.F., KinkerD.R. and ManganelloJ.J.. Automotive camshafts and tappets. SAE Tran., 1956, 64: 139-152.
- TanimotoI., KanoM. and SasakiM.. Establishment of a method for predicting cam follower wear in the material development process. SAE paper No. 902087, 1990.
- MatsuiT., KobayashiM., OkamuraH., KatoK. and HoriY.. Ceramic tappets cast in aluminum alloy for diesel engines. SAE paper No. 900403, 1990.
- KatoM. and KimuraY.. Quantitative analysis of cam follower wear in relation to various material properties. Wear, 1993, 162-164: 897-905.
- OhtsuboK. and TsusakaY.. Effects of disperant-detergent additives on engine wear. J.JST 23, 1978, 10: 703-708.
- AokiM., IkezawaH. and YoshidaH.. Effects of engine additives on valve-train wear. J.JSAE, 1983, 37(1): 61-66.
- SmolenskiD.J. and KabelR.H.. Evaluation of camshaft and lifter wear, deposits, and oil thickening with low-phosphorus engine oils in taxicab service. SAE paper No. 861516, 1986.
- YoshidaK. and SakuraiT.. Mechanism of valve train wear caused by diesel soot. J.JST, 1988, 33(8): 629-636.
- HeldenA.K., MeerR.J., StaadenJ.J. and GelderenE.. Dynamic friction in cam/tappet lubrication. SAE paper No. 850441, 1985.
- SanadaM., YamashitaH. and IzawaS.. Method of enhancing wear resistance of cam and follower system in engine valve train. JSAE Review, 1991,12(4): 4-10.
- KanoM. and TanimotoI.. Wear mechanism of high wear-resistant materials for automotive valve trains. Wear, 1991, 151, 229-243.
- SoejimaM., MakuriY., EjimaY. et al.. Experimental evaluation of scuffing resistance of cam and follower. Proceeding of the International Tribology Conference, Tokohama, 1995, 1483-1488.
- RaoV.D.N., KabatD.M., ClionnekH.A. et al.. Material systems for cylinder bore applications-plasma spray technology. Journal of Automotive Engineering, 1997, 23, 99-139.
- SaitoK. et al.. Development of low friction solid lubricant film coated piston. J.JSAE, 1995, 943, 586-593.
- AstashkevichB.M.. Parts of a cylinder-and-piston group: friction, wear, and lubrication [in Russian]. Mashinostroenie, Moscow, 1979, 174-205.
- AstashkevichB.M.. Effect of porosity on the properties of a sintered powder material for piston rings of internal combustion engines. Metal Science and Heat Treatment, 1996, 38(7-8): 299-302.
- Andersson P., Tamminen J., and Sandström C-E., Piston ring tribology - A literature survey, VTT Research Report Notes 2178, VTT Industrial Systems, Metallimichenkiya, P.O. Box 1702, Finland 02044.
- KohlerH.W.. New piston ring materials reduce wear. Diesel & Gas Turbine Worldwide, 1998, 5: 22-24.
- YoshidaH. et al.. Effects of surface treatments on piston ring friction force and wear. SAE paper No. 900589, 1990.
- WangY.S., NarasimhanS. and LarsonJ.M.. A review of ceramic tribology and application of Si-based ceramics to engine valves/seat inserts. Journal of Automotive Engineering, 1996, 304, 330-342.
- LumbyR.J., HodgsonP., Cother N.E. et al.. Syalon ceramics for advanced engine components. SAE paper No. 850521, 1985.
- NishiokaT., MatsunumaK., YamamotoT. et al. Development of high strength Si3N4 sintered body for the valve systems of automotive engines. SAE paper No. 920384, 1992.
- KabatD.M., GarwinI.J. and HartsockD.L.. Ceramic valve analysis, reliability and test results. SAE paper No. 880670, 1988.
- AsnaniM. and KuonenF.L.. Ceramic valve and seat insert performance in a diesel engine. SAE paper No. 850358, 1985.
- HoriY., MiyakawaY., AsamiS. et al.. Si3N4 ceramic valves for internal combustion engines. SAE paper No. 890175, 1989.
- UpdikeS.H. and NagleP.D.. Ceramic valve train components. SAE paper No. 880441, 1988.
- UpdikeS.H.. A comparison of wear mechanics with ceramic and metal valves in firing engines. SAE paper No. 890177, 1989.
- SchreinerM., LiangW., KamoR. et al.. Ceramic valve train materials investigation for advanced industrial natural gas engine. SAE paper No. 870418, 1987.
- LaceyP.I., HsuS.M., GatesR.S. et al.. Wear mechanisms of valves and valve seat inserts in a gas-fired reciprocating engine. NIST Special Publication, NISTIR 90-4246, 1990.
- MorgenthalerK.D.. Ceramics in the automobile. Symposium on Grinding of High-Performance Ceramics, Kaiserslautern, Germany, Oct. 19-20, 1994.
- RodriguesH.. Sintered valve seat inserts and valve guides: Factors affecting design, performance and machinability. Valve Train System Design and Materials, Materials Park, OH, ASM International, 1997.
- PopoolaO.O., ReatherfordL.V. and MccuneR.C.. Process and materials development for adherently sprayed valve seats on aluminum engine heads. Journal of Automotive Engineering, 1998, 329, 201-208.
- Jarratt M., Zhang X., and Teer T., An advanced DLC coating with exceptional wear properties, Technical Brochure, Teer Coatings Ltd., West Stone House, Berry Hill Industrial Estate, Droitwich, Worcs, United Kingdom, WR9 9AS.
- KanoM.. Wear resistance properties of ion-plated coatings on cam followers. Proceeding of the International Tribology Conference, Yokohama, 1995.
- Patterson D.J., Hill S.H. and Tung S.C., “Bench wear testing of engine power cylinder components”, Lubrication Engineering, 1993, Vol. 49, No. 2, p. 89-95.
- Hartfield-Wunsch S.E., Tung S.C. and Rivard C.J., “Development of a bench wear test for the evaluation of engine cylinder components and the correlation with engine test results”, SAE Technical Paper Series, Paper Number 932693, 1993.
- Blau P.J., A review of sub-scale test methods to evaluate the friction and wear of ring and liner materials for spark- and compression ignition engines, Oak Ridge National Laqboratory Report, Report Number ORNL/TM-2001/184, November 2001.
- HillS.H. and TungS.C.. Bench wear testing of common gasoline engine cylinder bore surface/piston ring combinations. Tribology Transactions, 1996, 39(4): 929-935.
- TingL.L.. Development of a reciprocating test rig for tribological studies of piston engine moving components- Part 1: Rig design and piston ring friction coefficient measuring method. SAE paper No. 930685, 1993.
- HargreavesD.J. et al.. Development of a reciprocating wear test rig and computer program for tribological studies of piston ring-liner contact. Transactions of Mechanical Engineering, IEAust., 1995, ME20(2): 99-104.
- HartfieldS.E., TungS.C. and RivardC.J.. Development of a bench wear test for the evaluation of engine cylinder components and the correlation with engine test results. SAE paper No. 932693, 1993, 1131-1138.
- PattersonD.J., HillS.H. and TungS.C.. Bench wear testing of engine power cylinder components. Lubrication Engineering,1993, 2, 89-95.
- BalnavesM., CzarkowskiD., GianniniR. et al.. Fuel property effects on ring and liner wear rates in a DDC 6V-53T using SLA techniques. SAE paper No. 912326, 1991.
- PritzS.G. and CataldiG.R.. In situ piston ring wear measurements in a medium-speed diesel engine. Lubrication Engineering, 1990, 6, 365-370.
- HeneinN.A., MaA. and GlidewellJ.. In situ wear measuring technique in engine cylinders. Tribology Transactions, 1998, 41(4): 579-585.
- HarariR. and SherE.. Measurement of engine friction power by using inertia tests. SAE paper No. 950028, 1995, 16-20.
- KoikeN., KumagaiY. and NakamuraK.. Development of detection system for abnormal wear of engine bearings. JSAM Review, 1998,19, 27-32.
- COST 532 Conference, European Concerted Action on Triboscience and Tribotechnology: Superior friction and wear control in engines and transmissions,October 18-19, 2004, Ghent, Belgium, http://ltds.eclyon.fr/cost532/projects_proposal_status_se pt_02/proposals-pdf-files/C532-PP-M15-01-02.pdf