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Near-Frictionless Carbon Coatings for Use in Fuel Injectors and Pump Systems Operating with Low-Sulfur Diesel Fuels
Technical Paper
2000-01-0518
ISSN: 0148-7191, e-ISSN: 2688-3627
Annotation ability available
Sector:
Event:
SAE 2000 World Congress
Language:
English
Abstract
While sulfur in diesel fuels helps reduce friction and prevents wear and galling in fuel pump and injector systems, it also creates environmental pollution in the form of hazardous particulates and SO2 emissions. The environmental concern is the driving force behind industry's efforts to come up with new alternative approaches to this problem. One such approach is to replace sulfur in diesel fuels with other chemicals that would maintain the antifriction and antiwear properties provided by sulfur in diesel fuels while at the same time reducing particulate emissions. A second alternative might be to surface-treat fuel injection parts (i.e., nitriding, carburizing, or coating the surfaces) to reduce or eliminate failures associated with the use of low-sulfur diesel fuels.
Our research explores the potential usefulness of a near-frictionless carbon (NFC) film developed at Argonne National Laboratory in alleviating the aforementioned problems. The lubricity of various diesel fuels (i.e., high-sulfur, 500 ppm; low sulfur, 140 ppm; ultra-clean, 3 ppm; and synthetic diesel or Fischer-Tropsch, zero sulfur) were tested by using both uncoated and NFC-coated 52100 steel specimens in a ball-on-three-disks and a high-frequency reciprocating wear-test rig. The test program was expanded to include some gasoline fuels as well (i.e., regular gasoline and indolene) to further substantiate the usefulness of the NFC coatings in low-sulfur gasoline environments. The results showed that the NFC coating was extremely effective in reducing wear and providing lubricity in low-sulfur or sulfur-free diesel and gasoline fuels. Specifically, depending on the wear test rig, test pair, and test media, the NFC films were able to reduce wear rates of balls and flats by factors of 8 to 83. These remarkable reductions in wear rates raise the prospect for using the ultra slick carbon coatings to alleviate problems that will be caused by the use of low sulfur diesel and gasoline fuels. Surfaces of the wear scars and tracks were characterized by optical and scanning electron microscopy, and by Raman spectroscopy.
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Authors
Topic
Citation
Erdemir, A., Ozturk, O., Alzoubi, M., Woodford, J. et al., "Near-Frictionless Carbon Coatings for Use in Fuel Injectors and Pump Systems Operating with Low-Sulfur Diesel Fuels," SAE Technical Paper 2000-01-0518, 2000, https://doi.org/10.4271/2000-01-0518.Also In
References
- Nikanjam M. Henderson P. T. “Lubricity of Aromatic Diesel Fuels,” SAE Tech. Paper No: 920825 1992
- Wei D. Spikes H. A. “The Lubricity of Diesel Fuels,” Wear 111 217 235 1986
- Shukla B. M. Bisht R. P. S. Pundir B. P. “Laboratory Method for Assessing Lubricity Characteristics of Diesel Fuels,” Petroleum Science and Technology 9-10 805 821 1997
- Wang J. C. Reynolds D. J. “The Lubricity Requirement of Low Sulfur Diesel Fuels,” SAE Paper No: 942015 1994
- Wang J. C. Cusano C. M. “Predicting Lubricity of Low Sulfur Diesel Fuels,” SAE Paper No: 952564 1995
- Nikanjam M. “Diesel Fuel Lubricity Additive Study,” SAE Paper No: 942014 1994
- Nikanjam M. “Diesel Fuel Lubricity: On the Path to Specifications,” SAE Paper No: 1999-01-1479
- Gray C. D. Webster G. D. Voitik R. M. Pierre P. ST Michell K. “Falex Ball-on-Three Disk (BOTD-M2) Uset to Determine the Low Temperature Lubricity and Associated Characteristics of Lubricty Additives for Diesel Fuels,” Proc. 2 nd Int. Colloquim on Fuels Bartz W. J. Technische Akademie Esslingen Ostfildern, Germany 211 217 1999
- Kajdas C. Majzener M. “Boundary Lubrication of Low-sulfur Diesel Fuel in the Presence of Fatty Acids,” Proc. 2 nd Int. Colloquim on Fuels Bartz W. J. Technische Akademie Esslingen Ostfildern, Germany 219 238 1999
- Erdemir A. Switala M. Wei R. Wilbur P. “A tribological investigation of the graphite-to-diamond-like behaviour of amorphous carbon films ion beam deposited on ceramic substrates,” Surface and Coatings Technology 50 17 23 1990
- Erdemir A. “Tribology of hard carbon films under extreme sliding conditions,” Proc. COST-516 Trib. Symp. Ronkainen, H. Holmberg, K. VTT-Helsinki Finland 38 56 1998
- Erdemir A. Nichols F. Pan X. Wei R. Wilbur P. “Friction and Wear Performance of Ion-Beam-Deposited Diamondlike Carbon Films on Steel Substrates,” Diamond Rel. Mat. 3 119 124 1993
- Erdemir A. Bindal C. Fenske G. R. Wilbur P. Tribological properties of hard carbon films on zirconia ceramics Tribol. Trans. 39 735 741 1996
- Erdemir A. Bindal, C. Pagan J. Wilbur, P. Characterization of Transfer Layers on Steel Surfaces Sliding Against Diamondlike Carbon in Dry Nitrogen Surf. Coat. Technol. 76-77 559 563 1995
- Erdemir A. Fenske G. R. Terry J. Wilbur P. “Effect of Source Gas and Deposition Method on Friction and Wear Performance of Diamondlike Carbon Films” Surf. Coat. Tech. 94-95 525 530 1997
- Erdemir A. Nilufer I. B. Eryilmaz O. L. Beschliesser M. Fenske G. R. “Friction and Wear Performance of Diamondlike Carbon Films Grown in Various Source Gas Plasmas,” Surf. Coat. Technol. 120-121 589 593 1999
- DeGaspari J. “Super-Slick Carbon” Mechanical Engineering 121 4 46 48 1999
- Robertson S. D. Hitchings G. J. Lin J. “Lubricity for Modern Diesel Fuels,” Proc. Slotrib 96 Vizintin J. University of Lujbljana Solvenia 87 102