This content is not included in
your SAE MOBILUS subscription, or you are not logged in.
2-Butanone Laminar Burning Velocities - Experimental and Kinetic Modelling Study
Technical Paper
2015-01-1956
ISSN: 0148-7191, e-ISSN: 2688-3627
Annotation ability available
Sector:
Language:
English
Abstract
2-Butanone (C4H8O) is a promising alternative fuel candidate as a pure as well as a blend component for substitution in standard gasoline fuels. It can be produced by the dehydrogenation of 2-butanol. To describe 2-butanone's basic combustion behaviour, it is important to investigate key physical properties such as the laminar burning velocity. The laminar burning velocity serves on the one hand side as a parameter to validate detailed chemical kinetic models. On the other hand, especially for engine simulations, various combustion models have been introduced, which rely on the laminar burning velocity as the physical quantity describing the progress of chemical reactions, diffusion, and heat conduction. Hence, well validated models for the prediction of laminar burning velocities are needed. New experimental laminar burning velocity data, acquired in a high pressure spherical combustion vessel, are presented for 1 atm and 5 bar at temperatures of 373 K and 423 K. An already existing mechanism, thoroughly validated with shock tube and rapid compression machine data, is compared against the new experimental data. It was found that the mechanism needs improvement with respect to correctly predicting temperature and pressure sensitivity. In addition, a linear and a non-linear post-processing technique are used to estimate the laminar flame speed in the burnt. Depending on the experimental conditions, such as temperature, pressure, and equivalence ratio, the extrapolation methods significantly differ in results. Thus, it has to be carefully assessed which extrapolation technique is the correct choice.
Authors
Citation
Beeckmann, J., Hesse, R., Cai, L., Pitsch, H. et al., "2-Butanone Laminar Burning Velocities - Experimental and Kinetic Modelling Study," SAE Technical Paper 2015-01-1956, 2015, https://doi.org/10.4271/2015-01-1956.Also In
References
- Spindelbalker C. and Schmidt A. Sauerstohaltige kraftstoffextender Erdoel, Erdgas, Kohle 10 469 474 1986
- Beeckmann J. , Cai L. , and Pitsch H. Experimental investigation of the laminar burning velocities of methanol, ethanol, n-propanol, and n-butanol at high pressure Fuel 117 Part A(0) 340 350 2014
- Settles Gary S. Schlieren and Shadowgraph Techniques: Visualizing Phenomena in Transparent Media 2 Springer Berlin 2001
- Luminus Devices, Inc. CBT-120 Product Datasheet 2011
- Poling B. , Prausnitz J. , and Connell J.O. The Properties of Gases and Liquids McGraw Hill professional. McGraw-Hill 2000
- Beeckmann J. , Chaumeix N. , Dagaut P. , Dayma G. , Foucher F. , Halter F. , Lefebvre A. , Mounaim-Rousselle C. , Pitsch H. , Renou B. , and Varea E. Collobartive study for accurate measurements of laminar burning velocity 6th European Combustion Meeting Lund, Sweden 2013
- NIST Chemistry WebBook 2-butanone http://webbook.nist.gov/cgi/cbook.cgi?ID=78-93 National Institute of Standards and Technology
- GESTIS Substance Database for 2-butanone http://gestis-en.itrust.de/nxt/gateway.dll?f=templates$fn=default.htm$vid=gestiseng:sdbeng
- Pitsch H. Flamemaster: A C++ computer program for 0D combustion and 1D laminar flame calculations 1998
- Serinyel Z. , Chaumeix N. , Black G. , Simmie J.M. , and Curran H.J. Experimental and chemical kinetic modeling study of 3-pentanone oxidation The Journal of Physical Chemistry A 114 46 12176 12186 2010
- Serinyel Z. , Black G. , Curran H.J. , and Simmie J.M. A shock tube and chemical kinetic modeling study of methy ethyl ketone oxidation Combustion Science and Technology 182 4 6 574 587 2010
- 3-pentanone mechansim NUI Galway http://c3.nuigalway.ie/3pentanone.html
- Pichon S. , Black G. , Chaumeix N. , Yahyaoui M. , Simmie J.M. , Curran H.J. , and Donohue R. The combustion chemistry of a fuel tracer: Measured flame speeds and ignition delays and a detailed chemical kinetic model for the oxidation of acetone Combustion and Flame 156 2 494 504 2009
- Chen Z. , Burke M.P. , and Ju Y. Effects of Lewis number and ignition energy on the determination of laminar flame speed using propagating spherical flames Proceedings of the Combustion Institute 32 1 1253 1260 2009
- Bradley D. , Gaskell P.H. , and Gu X.J. Burning velocities, Markstein lengths, and flame quenching for spherical methane-air flames: a computational study Combustion and Flame 104 1 176 198 1996
- Bradley D. , Hicks R.A. , Lawes M. , Sheppard C.G.W. , and Woolley R. The measurement of laminar burning velocities and Markstein numbers for iso-octane-air and iso-octane-n-heptane-air mixtures at elevated temperatures and pressures in an explosion bomb Combustion and Flame 115 1 126 144 1998
- Starikovskii A. Y. Plasma supported Combustion Proceedings of the Combustion Institute 30 2 2405 2417 2005
- Otsu N. A threshold selection method from gray-level histograms IEEE transaction on systems and cybernetics 9 1 62 66 1979
- Williams F.A. Combustion theory : the fundamental theory of chemically reacting flow systems Combustion Science and Engineering Series Menlo Park, Calif. Benjamin/Cummings Pub. Co. 1985
- Clavin P. and Williams F.A. Effects of molecular diffusion and of thermal expansion on the structure and dynamics of premixed flames in turbulent flows of large scale and low intensity Journal of Fluid Mechanics 116 251 282 1982
- Pelce P. and Clavin P. Influence of hydrodynamics and diffusion upon the stability limits of laminar premixed flames Journal of Fluid Mechanics 124 219 237 1982
- Matalon M. and Matkowsky B.J. Flames as gasdynamic discontinuities Journal of Fluid Mechanics 124 239 259 1982
- Wu C.K. and Law C.K. On the determination of laminar flame speeds from stretched flames. Symposium (International) on Combustion 20 1 1941 1949 1985
- Halter F. , Tahtouh T. , and Mounaim-Rousselle C. Nonlinear effects of stretch on the flame front propagation Combustion and Flame 157 10 1825 1832 2010
- Ronney P.D. and Sivashinsky G.I. A theoretical study of propagation and extinction of nonsteady spherical flame fronts SIAM Journal on Applied Mathematics 49 4 1029 1046 1989
- Kelley A.P. and Law C.K. Nonlinear effects in the experimental determination of laminar flame properties from stretched flames In Fall technical meeting: eastern states sections of the Combustion Institute Virginia 2007
- Kelley A.P. and Law C.K. Nonlinear effects in the extraction of laminar flame speeds from expanding spherical flames Combustion and Flame 156 9 1844 1851 2009