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Comparative Study on Performance and Emission Characteristics of Fish Oil Biodiesel and Mahua Oil Biodiesel Blend with Diesel and Diesel Fuel in a Medium Capacity Compression Ignition Employing Urea-SCR with Cu-ZSM5
Technical Paper
2014-01-1499
ISSN: 0148-7191, e-ISSN: 2688-3627
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English
Abstract
The present world scenario faces a serious threat from increasing dependence on fossil fuels. This has triggered the awareness to find alternative energy as their sustainable energy sources. Biodiesel as a cleaner renewable fuel may be considered as a good substitution for diesel fuel due to it being used in any compression ignition engine without any modification. The main advantages of using biodiesel are its renewability and better quality of exhaust gas emissions. In terms of emissions from biodiesel, the cause of concern continues to be the NOx emissions. Therefore, to compliment the functioning of biodiesels, Urea-SCR over Cu-ZSM5 catalyst is an effective option due to its ability to convert NOx into nitrogen and water. There has been increasing concerns that biodiesel feedstock may compete with food supply in the long term. The recent paper focuses on use of two non-edible oils mahua oil and fish oil (processed from waste produced by fish). The acid number of fish oil was found to be lower than mahua oil. Hence, the base catalyzed transesterification process was employed for production of fish oil methyl ester. On the other hand, mahua oil due to its higher free fatty acid content was esterified first and then, transesterified. B20 blend of biodiesels were used since it balances the property differences with conventional diesel e.g. performance, emission benefits and cost. Further, B20 blend can be used in automotive engines with no major modification. The present study focuses on the comparison of performance and emission characteristics of mahua oil biodiesel blends and fish oil biodiesel blends with diesel along with the employment of Urea-SCR as an exhaust treatment technology. The urea injection points have been varied along the exhaust pipe to study the dependence of distance between the engine exhaust and the SCR catalyst on the NOx emissions. The result shows the greater reduction of NOx for fish oil biodiesel and the brake thermal efficiency of fish oil biodiesel was found to be higher.
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Sharma, S., Gupta, S., Kumar, N., and Kumar, S., "Comparative Study on Performance and Emission Characteristics of Fish Oil Biodiesel and Mahua Oil Biodiesel Blend with Diesel and Diesel Fuel in a Medium Capacity Compression Ignition Employing Urea-SCR with Cu-ZSM5," SAE Technical Paper 2014-01-1499, 2014, https://doi.org/10.4271/2014-01-1499.Also In
References
- Lin CY , Li RJ Fuel properties of biodiesel produced from the crude fish oil from the soapstock of marine fish Fuel 2009 90 1 130 6
- Alamu OJ , Waheed MA , Jekayinfa SO Effect of thanol-palm kernel oil ratio on alkali-catalyzed biodiesel yield Fuel 2008 87 8-9 1529 33
- Ghesti GF , Macedo JLD , Parente VCI , Dias JA , Dias SCL Synthesis, characterization and reactivity of Lewis acid/surfactant cerium trisdodecylsulfate catalyst for transesterification and esterification reactions Appl Catal 2009 355 1-2 139 47
- Wang Y , Wu H , Zong MH Improvement of biodiesel production by lipozyme TL IM-catalyzed methanolysis using response surface methodology and acyl migration enhancer Bioresour Technol 2008 99 15 7232 7
- Agarwal A.K. Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines Progress in Energy and Combustion Science 33 2007
- Monyem A , Van gerpen JH , Canakci M The effect of timing and oxidation on emissions from biodieselfueled engines Trans Am Soc Agric Eng (ASAE) 2001 44 1 35 42
- Yamane K , Ueta A , Shimamoto Y Influence of physical and chemical properties of biodiesel fuel on injection, combustion and exhaust emission characteristics in a DI-CI engine 5 th international symposium on diagnostics and modelling of combustion in internal combustion engines (COMODIA) 2001 402 09
- Dorado MP , Ballesteros E , Arnal JM , Gomez J , Lopez FJ Exhaust emissions from a diesel engine fuelled with transesterified waste olive oil Fuel 2003 82 1311 5
- Tat ME , Van Gerpen JH Measurement of biodiesel speed of sound and its impact on injection timing Final Report, National Renewable Energy Laboratory 2003
- Rosca , R. , Rakosi , E. , Manolache , G. , and Niculaua , M. Fuel and Injection Characteristics for a Biodiesel Type Fuel from Waste Cooking Oil SAE Technical Paper 2005-01-3674 2005 10.4271/2005-01-3674
- Choi CY , Reitz RD An experimental study on the effects of oxygenated fuel blends and multiple injection strategies on DI diesel engine emissions Fuel 1999 78 1303 17
- Murayama , T. , Zheng , M. , Chikahisa , T. , Oh , Y. et al. Simultaneous Reductions of Smoke and NOx from a DI Diesel Engine with EGR and Dimethyl Carbonate SAE Technical Paper 952518 1995 10.4271/952518
- Jacobson K , Gopinath R , Meher LC , Dalai AK Solid acid catalyzed biodiesel production from waste cooking oil Appl Catal 2008 85 1-2 86 91
- FAO-Food and Agriculture Organization The State of World fisheries and aqua Felture Rome 2006
- FAO-Food and Agriculture Organization Food outlook, global market analysis Rome 2008
- Performance and emission characteristics of a Kirloskar HA394 diesel engine operated on fish oil methyl esters Godiganur Sharanappa a,* , Ch. Murthy Suryanarayana b , Reddy Rana Prathap c Elsevier -Renewable Energy 35 2010 355 359
- Preto F. , Zhang F. , Wang J. Fish oil as an alternative fuel for conventional combustors The Arctic Energy Summit Anchorage Alaska 2007 2008
- Steigers J.A. Demonstrating the use of fish oil as fuel in a large stationary diesel engine Bechtel P.J. Advances in seafood byproducts conference proceedings Alaska Sea Grant, Fairbanks, AK 2002 187 200
- Alaska Industrial Development and Export Authority UniSea fish oil demonstration project yields positive results http://www.akenergyauthority.org/PDF%20files/Unisea.pdf2002
- Blythe N.X. Fish oil as an alternative fuel for internal combustion engines American Society of Mechanical Engineers Internal Combustion Engine Division(Publication) ICE 26 1996 85 92
- Alberta N.A. Aryee , R. Voort Frederik van de , Simpson Benjamin K. FTIR determination of free fatty acids in fish oils intended for biodiesel production Process Biochemistry 44 2009
- Godiganor S. , Murthy Ch.S. , Reddy R.P. Performance and emission characteristics of a Kirloskar HA394 diesel engine operated on fish oil methyl esters RenewableEnergy 30 2010 355 359
- Andersen Otto , Weinbach Jan-Erik Residual animal fat and fish for biodiesel production Potentials in Norway, Biomass and Bioenergy 34 2010 1183 1188
- Preto F. , Zhang F. , Wang J. A study on using fish oil as an alternative fuel for conventional combustors Fuel 87 2008 2258 2268
- Lin C.Y. , Li R.J. Fuel properties of biodiesel produced from the crude fish oil from the soapstock of marine fish Fuel Processing Technology 90 2009 130 136
- Ram BVB , Ramanathan V , Phuan S , Vedaraman N Indian chemical Engg. Journal 2004 14 2 12 15
- Phuan S , Vedaraman N , Sankaranarayanan G , Ram BVB Renewable energy 2005 30 1269 1278
- Azam MM , Waris A , Nahar NM Biomass and Bioenergy 2005 29 293 302
- Forzatti P. , Lietti L. , Tronconi E. Nitrogen oxides removal Horvath I.T. Industrial Encyclopedia of Catalysis Wiley New York 2002
- Heck R.H. , Farrauto R.J. , Gulati S.T. Catalytic Air Pollution Control John Wiley & Sons New York 2002
- Enderle , C. , Vent , G. , and Paule , M. BLUETEC Diesel Technology - Clean, Efficient and Powerful SAE Technical Paper 2008-01-1182 2008 10.4271/2008-01-1182
- Forzatti P. , Lietti L. , Nova I. , Tronconi E. Diesel NOx aftertreatment catalytic technologies: analogies in LNT and SCR catalytic chemistry Catal. Today 151 2010 202
- Bonzi R. , Lietti L. , Castoldi L. , Forzatti P. NOx removal over a double-bed NSR- SCR reactor configuration Catal. Today 151 2010 376
- Lietti L. , Nova I. , Tronconi E. , Forzatti P. Transient kinetic study of the SCR- DeNOx, reaction Catal. Today 45 1998 85
- Corbos E.C. , Haneda M. , Courtois X. , Marecot P. , Duprez D. , Hamada H. Cooperative effect of Pt-Rh/Ba/Al and FeZSM-5 catalysts for NO x reduction during periodic lean-rich atmosphere Catal. Commun. 10 2008 137
- Wilken N. , Wijayanti K. , Kamasamudram K. , Ferrier N.W. , Vedaiyan R. , Yezerets A. , Olsson L. Mechanistic investigation of hydrothermal aging of Febeta for ammonia SCR Appl. Catal. B 112 2012 58
- Corma A. , Fornés V. , Palomares E. Selective catalytic reduction of NOx on Febeta zeolites Appl. Catal. B 11 1997 233
- Koebel , M. and Strutz , E.O. 2003 Thermal and Hydrolytic Decomposition of Urea for Automotive Selective Catalytic Reduction Systems: Thermochemical and Practical Aspects Ind. Eng. Chem. Res. 42 2093
- Kleemann , M. , Elsener , M. Koebel , M. et al. 2000 Hydrolysis of Isocyanic Acid on SCR Catalysts Ind. Eng. Chem. Res. 39 4120
- Maurer , B. , Jacob , E. and Weisweiler , W. 1999 Modelgasuntersuchen mit NH 3 und Harnstoff als Reduktionsmittel fiir die katalytische NOx-Reduktion MTZ 60 308
- Koebel , M. and Elsener , M. 1992 Entstickung von Abgasen nach dem SNCR-Verfahren: Ammoniak oder Harnstoff als Reduktionsmittel? Chem. Ing. Tech. 64 934
- Piazzesi , G. , Devadas , M. , Kr6cher , O. et al 2006 Isocyanic Acid Hydrolysis over Fe-ZSM5 in Urea-SCR Catal. Commun. 7 600
- Jacob , E. 1990 Verfahren und Vorrichtung zur selektiven katalytischen NO∼-Reduktion in sauerstoffhaltigen Abgasen German Patent DE 4038054
- Piazzesi , G. , Kr6cher , O. , Elsener , M. et al. 2006 Adsorption and Hydrolysis of Isocyanic Acid on TiO 2 Appl. Catal. B 65 55
- Piazzesi , G. 2006 The Catalytic Hydrolysis of Isocyanic Acid (HNCO) in the Urea-SCR Process Ph.D. Thesis No. 16693 ETH Zurich
- Costigan , M. , Cary , R. and Dobson , S. 2001 Vanadium Pentoxide and Other Inorganic Vanadium Compounds Concise International Chemical Assessment Document 29 World Health Organization Geneva, Switzerland
- Sun , Q. , Gao , Z. , Chen , Y. , et al. 2001 Reduction of NO∼ with Ammonia over Fe/MFI: Reaction Mechanism Based on Isotopic Labeling J. Catal. 201 89
- Devadas , M. , Kr6cher , O. and Wokaun , A. 2005 Catalytic Investigation of Fe-ZSM5 in the Selective Catalytic Reduction of NO x with NH 3 React. Kin. Catal. Lett. 86 347
- Krocher , O. , Devadas , M. , Elsener , M. et al. 2006 Investigation of the Selective Catalytic Reduction of NO by NH 3 on FE-ZSM5 Monolith Catalysts Appl. Catal. B 66 208
- Aspects of Catalyst Development for mobile Urea-SCR - from vanadia-titania catalysts to metalexchanged zeolites .O Krocher*Paul Schrrer Institute Villigen, Switzerland
- Rahkamaa-Tolonen K. , Maunula T. , Lomma M. , Huuhtanen M. , Keiski R. Catal. Today 100 2005 217
- Schwidder M. , Kumar M.S. , Klementiev K. , Pohl M.M. , Brückner A. , Grünert W. J. Catal. 231 2005 314
- Kröcher O. , Devadas M. , Elsener M. , Wokaun A. , Söger N. , Pfeifer M. , Demel Y. , Mussmann L. App. Catal. B Environ 66 2006 208
- Wallin M. , Karlsson C.J. , Skoglundh M. , Palmqvist A. J. Catal. 218 2003 354
- Li M. , Yeom Y. , Weitz E. , Sachtler W.M.H. J. Catal. 235 2005 201
- Sjövall H. , Olsson L. , Fridell E. , Blint R.J. Appl. Catal. B: Environ 64 2006 180
- Delahay G. , Valade D. , Guzma-Vargas A. , Coq B. Appl. Catal. B: Environ 55 2005 149
- Sanli H , Canakci M Biodiesel production from various feed-stocks and their effects on the fuel properties J IndMicrobiolBiotechnol 2008 35 431 41
- Canakci M , Sanli J Effect of different alcohol and catalyst usage on biodiesel production from different vegetable oils Energy Fuels 2008 22 2713 9
- Ezeanyanaso , C. S. et al. Comparative analysis of rubber seed methyl ester with other methyl esters Global Journal of Pure and Applied Sciences 16 2 2010
- Heywood JB Internal combustion engines New York McGraw-Hill 1988
- Gumus M Evaluation of hazelnut kernel oil of Turkish origin as alternative fuel in diesel engines Renew Energy 2008 33 2448 57
- Huang ZH , Lu HB , Jiang DM , Zeng K , Liu B , Zhang JQ et al. Combustion behavior of a compression ignition engine fuelled with diesel/methanol blends under various fuel delivery advance angles Bio-resource Technology 2004 95 331 41
- Eastwood , P. Critical Topics in Exhaust Gas After treatment research Studies Press Baldock, U.K. 2000
- Maheshwari N. , Balaji C. , Ramesh A. A nonlinear regression based multi-objective optimization of parameters based on experimental data from an IC engine fueled with biodiesel blends biomass and bioenergy 35 2011
- Qi D.H. , Geng L.M. , Chen H. , Bian Y.ZH. , Liu J. , Ren X.CH. Combustion and performance evaluation Aspects of Catalyst Development for mobile Urea-SCR - from vanadia-titania catalysts to metal-exchanged zeolites .O Krocher*Paul Schrrer Institute Villigen, Switzerland