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Browse AllThe scheme of photocatalysis of water, a way of hydrogen generation as a clean, high-efficiency fuel source for aircraft and long-range transport systems has received considerable interest. The development of the covalent organic framework (COF) - derived materials for hydrogen evolution reaction (HER) has since become a research highlight. Compared to traditional methods, photocatalytic hydrogen evolution systems based on COFs can provide ways of generating hydrogen gas without depending upon noble metal catalysts, thereby enhancing the sustainability and prospects of this technology for future aerospace energy applications.In this work, two covalent organic frameworks (COFs) with distinct linkages—a vinylene-linked COF A (via Knoevenagel condensation) and an imine-linked COF B (via Schiff-base reaction)—were designed and synthesized to compare their performance in the photocatalystic hydrogen evolution reaction (HER). Structural and electrochemical characterizations confirmed that, despite lower crystallinity and specific surface area due to pore blockage, COF A exhibited a suitable band structure for photocatalysis and achieved an HER rate of 56 μmol h^–1 g^–1 under simulated sunlight. In contrast, COF B was ineffective. This study experimentally validates the superior photocatalytic potential of vinylene-linked COFs over imine-linked counterparts for HER, highlighting their potential as non-noble-metal catalysts for aerospace and transport-oriented fuel generation.
Ultrasonic TOFD detection is one of the most important non-destructive testing techniques for welds. However, the complex beam deflection, scattering, and attenuation of ultrasonic waves in the heterogeneous weld structure lead to the weak signal of the defect diffraction wave received by the probe and the low signal-to-noise ratio, which has a negative impact on the engineering application of ultrasonic TOFD detection technology in austenitic stainless steel welds. In this study, a numerical model of the ultrasonic TOFD detection process for austenitic stainless steel welds was established based on the finite element method. Combined with the test method, the interaction mechanism between the ultrasonic wave and weld structure is analyzed, and the probe arrangement method to reduce the interference of weld scattering noise is proposed. The results show that the finite element model can simulate the anisotropic characteristics of ultrasonic waves in austenitic stainless steel welds, including sound field distortion, sound energy scattering, and attenuation. Combined with the detection test, it has been proven that the adverse effect of the weld structure on the TOFD detection signal can be reduced by changing the probe detection surface.














