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Browse Allg-C₃N₄, a metal-free semiconductor photocatalyst, demonstrates remarkable potential, but its practical application in pollutant degradation is significantly limited by the rapid recombination of photogenerated electron-hole pairs and low photocatalytic efficiency. To address this, a series of magnetic recyclable g-C₃N₄/CoFe₂O₄ composite photocatalysts with different CoFe₂O₄ doping ratios were innovatively designed and prepared via thermal polymerization, sol- gel, and combined with ultrasonic and heat treatment processes. The novelty of this composite design lies in the effective integration of magnetic CoFe₂O₄ with g-C₃N₄ through a heterojunction structure. It substantially boosts the absorption of visible light. Concurrently, it effectively fosters the separation and mobility of photo-induced charge carriers. The composite materials were systematically characterized by X-ray diffraction, thermogravimetric analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy, photoluminescence spectroscopy, and ultraviolet-visible diffuse reflectance spectroscopy. Using tetracycline hydrochloride as the target pollutant, the photocatalytic activity of the composites was evaluated under visible light irradiation, and the effects of initial concentration, catalyst dosage, and the influence of solution pH on degradation efficiency were also examined. The results indicated that the composite with a CoFe₂O₄ to g-C₃N₄ mass ratio of 1:3 (denoted as 3-CN/CFO) exhibited the optimal performance: a TCH degradation rate of 80.29 % within 105 minutes and a total organic carbon removal rate of 61.63 %. After five consecutive cycling experiments, the degradation efficiency remained above 70 %, demonstrating good reusability and stability. The performance improvement is attributed to the formation of heterojunctions in the composite, which effectively facilitates charge separation, inhibits carrier recombination, and enhances visible light absorption. Furthermore, the inherent magnetism of the composite permits efficient recovery, streamlining its integration into practical applications. Toward the purification of antibiotic-contaminated water, this research proposes a viable method for fabricating highly effective and recyclable photocatalysts.
With the complexity of chemical warfare threats and the diversification of battlefield environments, traditional toxic agent detection methods are facing bottlenecks such as response delays, coverage blind spots, and personnel safety risks. This research focuses on the application of unmanned aerial vehicle (UAV) carried toxic agent sensor systems, aiming to analyze the methods of mounting and deploying the sensors on the UAVs, and to construct a rapid response, high-precision, and highly resistant toxic agent monitoring system. Its significance lies in two aspects: 1. Tactical value: It breaks through the time and space limitations of manual reconnaissance, realizes real-time dynamic perception and early warning of toxic agent contamination, and provides key decision-making support for battlefield command; 2. Application expansion: The research results can be transferred to counter-terrorism, nuclear, biological, and chemical emergency response fields, providing theoretical support and engineering paradigms for the development of unmanned and intelligent chemical defense equipment.
This study proposes an intelligent automotive roof frame design method based on the middle layer and component technology on CATIA. It aims to solve core roof modeling issues: determining geometric input quantity but uncertain attributes (tangent vectors, normal vectors, number of curve segments, number of surface patches, and boundaries), high manual interaction dependence, and poor knowledge reuse, to realize efficient design knowledge reuse. Methodologically, it builds a feature-driven parametric template, develops a knowledge rule-embedded componentized UDF library (reducing repeated modeling and geometric reconstruction needs), and integrates knowledge engineering for geometric input verification and operation direction control, eliminating curve/surface attribute uncertainty impacts. Verification shows the template stably generates roof crossbeams under simple/complex inputs, improving model robustness and reuse rate, reducing design workload, shortening verification cycles, and providing an extensible solution for white body design.
Impact testing utilizing instrumented hammers and accelerometers is a widely adopted technique in dynamic testing. The mass loading effect of the accelerometer alters the dynamic response of the test structure, leading to deviations between the measured frequency response functions (FRFs) and their true values. Furthermore, the effects on the FRFs are contingent upon the positioning of the accelerometer, thereby causing the measured FRFs between two points to fail to meet the principle of reciprocity. This paper investigates the compensation method for the mass of a single accelerometer in impact testing. Compensation formulas for both origin–FRF and cross–FRF are derived using the frequency domain substructure decoupling method. Numerical simulations on a cantilever beam and experimental tests with milling tools validate the proposed methodology. The compensation formulas for FRFs presented in this paper are expected to enhance the measurement accuracy of FRFs in modal testing of small structures, particularly relevant for lightweight components in aerospace, aircraft, and transportation systems, where precise dynamic characterization is critical.
This research develops a multi-arc cooperative additive fabrication to address the technical challenges of low forming efficiency and insufficient precision in the production of complex components using conventional single-arc additive manufacturing systems. With the core objective of achieving efficient and high-quality production of large high-performance metal parts, the equipment employs a modular architecture, incorporating four core modules: additive fabrication modular, 3D measurement module, subtractive machining module, and central control module. It creatively designs a multi-arc cooperative additive fabrication head assembly characterized by “two contours + one filling” arc layout, enabling synchronized operation of two contour single-wire arcs and an independently developed single-power three-wire oscillating filling arc. This system builds a multi-robot collaborative motion system based on the master-slave control strategy. It realizes time synchronization and trajectory synchronization of additive, measurement, and subtractive robots through the KUKA.RoboTeam software package. Meanwhile, it integrates a laser arc constraint device, a molten pool monitoring system, and a digital process parameter monitoring module. An integrated manufacturing capability of “additive - measurement - subtraction” is formed to enhance the forming efficiency and accuracy of components. Experimental verification shows that the forming efficiency of this equipment reaches 1800 cm^3/h, which is more than three times higher than that of traditional single-arc equipment. The surface roughness of the components is optimized to 41.50 μm, and the forming size error is controlled within ±0.5 μm. It can be adapted to the one-time forming of components with a width of 30 to 150 mm. It provides reliable technical support for the high-performance manufacturing of large metal components.