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Browse AllThere are three main methods for preparing chlorinated polyethylene: the solution method, suspension method, and solid-phase method. This article studies the process of preparing chlorinated polyethylene by the aqueous suspension method, introduces the production process of chlorinated polyethylene, first understands the reaction mechanism of the chlorination reaction, then explores the production process of chlorinated polyethylene by the suspension method, and finds the optimal process conditions through experiments. The results showed that the optimal reaction temperature for the chlorination reaction of chlorinated polyethylene was 135°C, the optimal amount of initiator was 3%, and the optimal amount of chlorine gas added was 1.5%/min. This article explores the influencing factors of the optimal reaction conditions, laying a theoretical foundation for industrial production after the suspension method.
Carbon materials, as typical dielectric loss media, possess the characteristics of low density, stable chemical properties, wide sources, and diverse existing forms, and have been attracting much attention in the microwave absorption field. Based on carbon materials, the rational design and construction of microscopic morphology and microscopic structure is an effective way to improve their microwave absorption performance. Up to now, unique microstructures such as hollow, core-shell, and porous have been widely used in the design of microwave absorption materials, and their performance improvement has also been reliably confirmed. This paper mainly focuses on the research of the preparation and microwave absorption performance of porous carbon foams (CF-x). Firstly, it achieves the fabrication of porous carbon foams by the one-step pyrolysis using readily available glucose and NH4Cl, avoiding the need for polymer templates or magnetic element incorporation. In addition, this paper focuses on investigating the effect of the dosage of NH4Cl on the pore structure and dielectric properties of CF-x, and it reveals the advantages of the foam structure in terms of enhancing microwave absorption performance.
The scheme of photocatalysis of water, a way of hydrogen generation as a clean, high-efficiency fuel source for aircraft and long-range transport systems has received considerable interest. The development of the covalent organic framework (COF) - derived materials for hydrogen evolution reaction (HER) has since become a research highlight. Compared to traditional methods, photocatalytic hydrogen evolution systems based on COFs can provide ways of generating hydrogen gas without depending upon noble metal catalysts, thereby enhancing the sustainability and prospects of this technology for future aerospace energy applications.In this work, two covalent organic frameworks (COFs) with distinct linkages—a vinylene-linked COF A (via Knoevenagel condensation) and an imine-linked COF B (via Schiff-base reaction)—were designed and synthesized to compare their performance in the photocatalystic hydrogen evolution reaction (HER). Structural and electrochemical characterizations confirmed that, despite lower crystallinity and specific surface area due to pore blockage, COF A exhibited a suitable band structure for photocatalysis and achieved an HER rate of 56 μmol h^–1 g^–1 under simulated sunlight. In contrast, COF B was ineffective. This study experimentally validates the superior photocatalytic potential of vinylene-linked COFs over imine-linked counterparts for HER, highlighting their potential as non-noble-metal catalysts for aerospace and transport-oriented fuel generation.
Ultrasonic TOFD detection is one of the most important non-destructive testing techniques for welds. However, the complex beam deflection, scattering, and attenuation of ultrasonic waves in the heterogeneous weld structure lead to the weak signal of the defect diffraction wave received by the probe and the low signal-to-noise ratio, which has a negative impact on the engineering application of ultrasonic TOFD detection technology in austenitic stainless steel welds. In this study, a numerical model of the ultrasonic TOFD detection process for austenitic stainless steel welds was established based on the finite element method. Combined with the test method, the interaction mechanism between the ultrasonic wave and weld structure is analyzed, and the probe arrangement method to reduce the interference of weld scattering noise is proposed. The results show that the finite element model can simulate the anisotropic characteristics of ultrasonic waves in austenitic stainless steel welds, including sound field distortion, sound energy scattering, and attenuation. Combined with the detection test, it has been proven that the adverse effect of the weld structure on the TOFD detection signal can be reduced by changing the probe detection surface.
P2-type layered oxides are good cathode materials in high-performance sodium-ion batteries since they have desirable two-dimensional ion migration pathways. However, their instability at interfaces and their attenuation as cycles persist also remain a significant challenge. To increase their electrochemical stability, surface coating is also a good plan, but the balance between the coating and ionic conductivity is one of the key challenges. This study constructed an immensely thin layer of alumina (Al2O3) coating, and the influence of the amount of the coating (0.3-1.2 wt percent) on the working of the material was methodically examined. Electrochemical analysis showed that the lowest levels of Al2O3 (0.3 wt) provide the greatest improvement in performance. The optimized sample showed a retention capacity of 96.35 after 100 cycles of operation at 1C, significantly higher compared with samples that had increased coating contents. An analysis of cyclic voltammetry and impedance spectroscopy was subsequently done to corroborate the presence of a 0.3 wt% coating, which infected the electrode-electrolyte interface by inhibiting side reactions but minimally obstructing sodium-ion transport and thus promoting reaction reversibility and improved interfacial kinetics. These results highlight the importance of a less-is-more rule when it comes to surface coating and provide a novel understanding of how long-life sodium-ion battery cathodes can be designed by carefully engineered interfaces.














